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8.22288
Periodic acid
for synthesis
Synonyma:
Periodic acid
Přihlásit pro zobrazení organizačních a smluvních cen.
Vybrat velikost
Změnit zobrazení
| Velikost balení | Skladová položka | Dostupnost | Cena |
|---|---|---|---|
| 100 g | Obraťte se na zákaznický servis a vyžádejte si informaci o dostupnosti. | 2 880,00 Kč | |
| 500 g | Obraťte se na zákaznický servis a vyžádejte si informaci o dostupnosti. | 9 010,00 Kč |
O této položce
Empirický vzorec (Hillův zápis):
H5IO6
Číslo CAS:
Molekulová hmotnost:
227.94
UNSPSC Code:
12352301
EC Index Number:
233-937-0
NACRES:
NA.22
MDL number:
Assay:
≥98% (iodometric)
Form:
solid
Grade:
synthesis grade
2 880,00 Kč
Obraťte se na zákaznický servis a vyžádejte si informaci o dostupnosti.
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synthesis grade
Quality Segment
assay
≥98% (iodometric)
form
solid
reaction suitability
reagent type: oxidant
pH
1.2 (20 °C, 100 g/L in H2O)
mp
122 °C
solubility
ethanol: soluble at 20 °C, water: soluble at 20 °C
bulk density
1400 kg/m3
storage temp.
15-25°C
SMILES string
[I](=O)(O)(O)(O)(O)O
InChI
1S/H5IO6/c2-1(3,4,5,6)7/h(H5,2,3,4,5,6,7)
InChI key
TWLXDPFBEPBAQB-UHFFFAOYSA-N
Application
Periodic acid can be used as a reagent for the oxidative cleavage of 1,2 diols to ketones or aldehydes, and epoxides to aldehydes. It is also used in the oxidative cleavage of various protecting groups such as acetonide, tetrahydropyranyl ether (THP), ethoxyethyl acetals, cyclic acetals, dithioacetals, and oxathioacetals.
It can also be used:
It can also be used:
- In the selective N-nitrosation of secondary amines in the presence of sodium nitrite, and wet silica gel.
- As a stoichiometric oxidant with chromium (IV) acetate for the oxidation of tertiary C−H bonds to tertiary alcohols.
- In combination with chromium oxide to oxidize primary alcohols to carboxylic acids; alkylbenzenes to benzoic acids; and cyclic benzyl ethers to the corresponding lactones.
- In the iodination of bulky polyalkyl benzenes in the presence of iodine.
- In the oxidative coupling of polycyclic aromatic hydrocarbons in the presence of aqueous acetic acid.
- In the selective oxidation of sulfides to sulfoxides using FeCl3 as a catalyst.
Analysis Note
Assay (iodometric): ≥ 98.0 %
Melting range (lower value): ≥ 124 °C
Melting range (upper value): ≤ 129 °C
Melting range (lower value): ≥ 124 °C
Melting range (upper value): ≤ 129 °C
1 of 1
Tato položka | |||
|---|---|---|---|
| grade synthesis grade | grade ACS reagent | grade - | grade - |
| assay ≥98% (iodometric) | assay 99%, 99.0-101.0% (ACS specification) | assay ≥99.0% | assay 99.999% trace metals basis |
| Quality Level 200 | Quality Level 200 | Quality Level 100 | Quality Level 200 |
| form solid | form powder or crystals | form powder or crystals | form crystals |
| solubility ethanol: soluble at 20 °C, water: soluble at 20 °C | solubility water: soluble | solubility water: 100 mg/mL, clear, colorless | solubility water: soluble |
| storage temp. 15-25°C | storage temp. - | storage temp. - | storage temp. - |
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signalword
Danger
Hazard Classifications
Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Ox. Sol. 1 - Skin Corr. 1B - STOT RE 1 Oral
target_organs
Thyroid
Skladovací třída
5.1A - Strongly oxidizing hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
hcodes
Osvědčení o analýze (COA)
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Dokumenty související s produkty, které jste v minulosti zakoupili, byly za účelem usnadnění shromážděny ve vaší Knihovně dokumentů.
Periodic Acid
Stengel JH, et al.
eEROS (Encyclopedia of Reagents for Organic Synthesis), 1-6 (2001)
One-pot hydrothermal synthesis and characterization of CoFe2O4 nanoparticles and its application as magnetically recoverable catalyst in oxidation of alcohols by periodic acid
Paul B, et al.
Materials Chemistry and Physics, 181, 99-105 (2016)
A mild and highly efficient oxidation of sulfides to sulfoxides with periodic acid catalyzed by FeCl3
Kim SS, et al.
Synthesis, 2002(17), 2484-2486 (2002)
Globální číslo obchodní položky
| Skladová položka | GTIN |
|---|---|
| 8222880100 | 04022536487861 |
| 8222880500 | 04027269076764 |
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