902217

Ir[dFFppy]₂-(4,4′-dCF₃bpy)PF₆

≥95%, powder or crystals

• Synonyma: Ir photocatalyst, Photocatalyst
• Empirický vzorec (Hillův zápis): C₃₄H₁₆F₁₈IrN₄P
• Číslo CAS: 2030437-92-2
• Molekulová hmotnost: 1045.68
• MDL number: MFCD27952560
• UNSPSC Code: 12161600
• NACRES: NA.22

Vlastnosti

• Název produktu: Ir[dFFppy]₂-(4,4′-dCF₃bpy)PF₆, ≥95%
• assay: ≥95%
• form: powder or crystals
• reaction suitability: core: iridium, reagent type: catalyst; reaction type: Photocatalysis
• mp: >300 °C
• photocatalyst activation: 450 nm
• SMILES string: [Ir+]741([NH]8=C(c9c7cc(cc9F)F)C=CC(=C8)F)([NH]5=CC(=CC=C5c6c4cc(cc6F)F)F)[NH]2=CC=C(C=C2C3=CC(=CC=[NH]31)C(F)(F)F)C(F)(F)F.F[P-](F)(F)(F)(F)F
• InChI key: UCNIZYCFAFBGQB-UHFFFAOYSA-N

Popis

Application

Under a dual catalytic copper/photoredox manifold, the Mes-Umemoto reagent has been demonstrated to be an excellent photocatalyst for the trifluoromethylation of alkyl halides and aryl halides to yield alkyl-CF₃ and aryl-CF₃ in high yields. In both cases, these reactions exhibit wide substrate scope with good functional group tolerance. More specifically, a variety of 5-membered and 6-membered heteroaryl halides can be readily converted to the corresponding trifluoromethylheteroarenes under mild conditions. For trifluoromethylation reactions, use with dMesSCF₃ (901466) and supersilanol (902489).

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Other Notes

A radical approach to the copper oxidative addition problem:Trifluoromethylation of bromoarenes

Catalytic alkylation of remote C-H bonds enabled by proton-coupled electron transfer

Bezpečnostní informace

• Skladovací třída: 11 - Combustible Solids
• wgk: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable