87368-M

Tetrahydrofuran

≥99.9%, ACS reagent, contains ~0.025% 2, 6-di-tert-butyl-4-methylphenol as stabilizer, 250 ppm BHT as inhibitor, suitable for solid phase extraction (SPE), reag. Ph. Eur.

• Synonyma: THF, Butylene oxide, Oxolane, Tetramethylene oxide
• Lineární vzorec: (CH₂)₃CH₂O
• Číslo CAS: 109-99-9
• Molekulová hmotnost: 72.11
• NACRES: NA.21
• PubChem Substance ID: 329769580
• UNSPSC Code: 12352005
• EC Number: 203-726-8
• MDL number: MFCD00005356
• Beilstein/REAXYS Number: 102391
• Assay: ≥99.9%
• Technique(s): solid phase extraction (SPE): suitable
• Bp: 65-67 °C (lit.)
• Vapor pressure: 114 mmHg ( 15 °C), 143 mmHg ( 20 °C)

Vlastnosti

• Název produktu: Tetrahydrofuran, contains 250 ppm BHT as inhibitor, puriss. p.a., ACS reagent, reag. Ph. Eur., ≥99.9%
• Quality Segment: 200
• agency: reag. Ph. Eur.
• vapor density: 2.5 (vs air)
• vapor pressure: 114 mmHg ( 15 °C), 143 mmHg ( 20 °C)
• grade: ACS reagent, puriss. p.a.
• assay: ≥99.9%
• form: liquid
• autoignition temp.: 610 °F
• contains: 250 ppm BHT as inhibitor, ~0.025% 2,6-di-tert-butyl-4-methylphenol as stabilizer
• expl. lim.: 1.8-11.8 %
• technique(s): solid phase extraction (SPE): suitable
• impurities: ≤0.001% free acid (as CH₃COOH), ≤0.005% peroxides (as H₂O₂), ≤0.05% water
• evapn. residue: ≤0.001%
• refractive index: n20/D 1.407
• pH: ~7
• bp: 65-67 °C (lit.)
• mp: −108 °C (lit.)
• density: 0.887 g/mL at 20 °C, 0.889 g/mL at 25 °C (lit.)
• SMILES string: C1CCOC1
• cation traces: Al: ≤0.5 mg/kg, B: ≤0.02 mg/kg, Ba: ≤0.1 mg/kg, Bi: ≤0.1 mg/kg, Ca: ≤0.5 mg/kg, Cd: ≤0.05 mg/kg, Co: ≤0.02 mg/kg, Cr: ≤0.02 mg/kg, Cu: ≤0.02 mg/kg, Fe: ≤0.1 mg/kg, K: ≤0.5 mg/kg, Li: ≤0.1 mg/kg, Mg: ≤0.1 mg/kg, Mn: ≤0.02 mg/kg, Mo: ≤0.1 mg/kg, Na: ≤0.5 mg/kg, Ni: ≤0.02 mg/kg, Pb: ≤0.1 mg/kg, Sn: ≤0.1 mg/kg, Sr: ≤0.1 mg/kg, Zn: ≤0.1 mg/kg
• InChI: 1S/C4H8O/c1-2-4-5-3-1/h1-4H2
• InChI key: WYURNTSHIVDZCO-UHFFFAOYSA-N

Popis

General description

The product is tetrahydrofuran (THF) and it contains 250ppm BHT (Butylated hydroxytoluene) as an inhibitor. THF is widely employed as a solvent. It constitutes the key fragment of various natural products (polyether antibiotics). THF forms double hydrate with hydrogen sulfide. Crystal structure of this double hydrate has been investigated by three-dimensional single-crystal studies. Butane-1,4-diol is formed as an intermediate during the synthesis of THF. Hot THF is useful for the dissolution of polyvinylidene chloride (PVDV).

Application

Tetrahydrofuran has been used as a solvent for the preparation of sol-gel solution for coating solid phase microextraction (SPME) fibers in a study.

It may be used for the dissolution of poly-ε-caprolactone (PCL) and 1,3-diaminopentane, during the preparation of poly-ε-caprolactone (PCL)-hydroxyapatite (HA) scaffolds[1] and acrylate-terminated poly(5-amino-1-pentanol-co-1,4-butanediol diacrylate) (C32)- 1,3-diaminopentane (117) polymer,[2] respectively.

Analysis Note

miscible with water and ethanol (96%) pass

Other Notes

Sales restrictions may apply

Bezpečnostní informace

• signalword: Danger
• supp_hazards: EUH019
• Skladovací třída: 3 - Flammable liquids
• flash_point_f: 1.4 °F - closed cup
• flash_point_c: -17.00 °C - closed cup
• pictograms: GHS02,GHS08,GHS05,GHS07
• hcodes: H225,H302,H318,H335,H336,H351
• pcodes: P202 - P210 - P280 - P301 + P312 - P305 + P351 + P338 - P308 + P313
• Hazard Classifications: Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - STOT SE 3
• target_organs: Central nervous system, Respiratory system