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402869

Chloramine T trihydrate

ACS reagent grade, 98%, powder

Synonyma:

N-Chloro-p-toluenesulfonamide sodium salt

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Vybrat velikost

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Velikost baleníSkladová položkaDostupnostCena
100 g
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1 390,00 Kč
1 kg
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4 720,00 Kč

O této položce

Lineární vzorec:
CH3C6H4SO2NClNa · 3H2O
Číslo CAS:
Molekulová hmotnost:
281.69
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
204-854-7
MDL number:
Beilstein/REAXYS Number:
3924168
Assay:
98%, 98.0-103.0% (ACS specification)
Form:
powder

1 390,00 Kč


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Název produktu

Chloramine T trihydrate, ACS reagent, 98%

grade

ACS reagent

Quality Segment

assay

98%, 98.0-103.0% (ACS specification)

form

powder

reaction suitability

reagent type: oxidant

impurities

<1.5% insolubles (alcohol)

pH

8.0-10.0 (25 °C, 5%)

mp

167-170 °C (lit.)

solubility

H2O: passes test

suitability

passes test for determination of bromide

SMILES string

O.O.O.Cc1ccc(cc1)S(=O)(=O)N([Na])Cl

InChI

1S/C7H7ClNO2S.Na.3H2O/c1-6-2-4-7(5-3-6)12(10,11)9-8;;;;/h2-5H,1H3;;3*1H2/q-1;+1;;;

InChI key

NZYOAGBNMCVQIV-UHFFFAOYSA-N

General description

Chloramine T (CAT) trihydrate is a commonly used reagent for organic synthesis especially in heterocyclic chemistry. CAT is an active chlorine compound that shows antimicrobial activity.[1]

Application

Chloramine T trihydrate may be used as an oxidizing agent in the synthesis of 8-chloro-[1,2,4]triazolo[4,3-a]pyrazine derivatives and novel isoxazolines.
It may also be used in the synthesis of the following compounds:
  • Nitrile imines by the oxidative dehydrogenation of N-(nitrobenzyl)-imidazole aldehyde hydrazine.
  • Mono-N-tosylated-1,2-diamines.
  • 3,5-Disubstituted isoxazoles.[2]
  • Fused 3,6-disubstituted triazolothiadiazoles by the oxidative cyclization of N-heteroaryl-substituted hydrazones.
Nitrene source for aziridinations[3][4] and aminohydroxylations.[5]

Packaging

Capable of oxidative cyclization to produce various heterocycles.

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Tato položka
23270312241.02424
assay

98%, 98.0-103.0% (ACS specification)

assay

≥98.0% (RT)

assay

98.0-103.0%

assay

98.0-103.0% (iodometric)

solubility

H2O: passes test

solubility

-

solubility

-

solubility

150 g/L

reaction suitability

reagent type: oxidant

reaction suitability

reagent type: oxidant

reaction suitability

-

reaction suitability

-

Quality Level

200

Quality Level

200

Quality Level

100

Quality Level

200

form

powder

form

-

form

-

form

solid

mp

167-170 °C (lit.)

mp

167-170 °C (lit.)

mp

167-170 °C (lit.)

mp

-


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Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Resp. Sens. 1 - Skin Corr. 1B

supp_hazards

Skladovací třída

8A - Combustible corrosive hazardous materials

wgk

WGK 2

flash_point_f

377.6 °F - closed cup

flash_point_c

192 °C - closed cup



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Facile Synthesis of 3, 6-Disubstituted-1, 2, 4-triazolo-[3, 4-b]-1, 3, 4-thiadiazoles via Oxidative Cyclization of N-Heteroaryl-Substituted Hydrazones and Their Biological Activity.
Himaja M, et al.
Journal of Heterocyclic Chemistry, 49(4), 823-828 (2012)
Synthesis and antimicrobial activity of novel isoxazolines by 1, 3-dipolar cycloaddition reactions.
Govindaraju M, et al.
International Journal of ChemTech Research, 6(2), 886-890 (2014)
[1-(4-Nitrobenzyl)-2-butyl-4-chloro-1H-imidazol-5-yl]-4, 5-dihydro-1-phenyl-1H-pyrazole: Synthesis, Anti-Inflammatory and Analgesic Activities.
Sreenivasa S and Shankar BJ.
Open Journal of Medicinal Chemistry, 3(2) (2013)



Globální číslo obchodní položky

Skladová položkaGTIN
402869-1KG04061831986105
402869-100G04061835365722

Questions

1–3 of 3 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  3. what is the expiry date?

    1 answer
    1. This product is not assigned an expiration date or recommended retest date. Products with no expiration date or recommended retest date should be routinely inspected by customers to ensure they perform as expected. These products are also subject to a one year warranty from the date of shipment. For more information you may access the "Product Dating Information" document under "ADDITIONAL USEFUL DOCUMENTS ABOUT OUR PRODUCTS" at the bottom of the Quality Services page with this link: https://www.sigmaaldrich.com/life-science/quality-and-regulatory-management/quality-services.

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