11291

1-Ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide

≥97.0% (NMR)

• Synonyma: EMIM BTI, EMIM TFSI, EMIMIm
• Empirický vzorec (Hillův zápis): C₈H₁₁F₆N₃O₄S₂
• Číslo CAS: 174899-82-2
• Molekulová hmotnost: 391.31
• MDL number: MFCD03788927
• UNSPSC Code: 12352100
• PubChem Substance ID: 329749349
• NACRES: NA.22

Vlastnosti

• Quality Level: 100
• assay: ≥97.0% (NMR)
• form: liquid
• impurities: <0.5% water
• mp: ≥−15 °C (lit.)
• SMILES string: CCn1cc[n+](C)c1.FC(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F
• InChI: 1S/C6H11N2.C2F6NO4S2/c1-3-8-5-4-7(2)6-8;3-1(4,5)14(10,11)9-15(12,13)2(6,7)8/h4-6H,3H2,1-2H3;/q+1;-1
• InChI key: LRESCJAINPKJTO-UHFFFAOYSA-N

Popis

General description

1-Ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide [EMIM][N(Tf)₂] is a room temperature ionic liquid (RTIL). ([EMIM][N(Tf)₂]) as a non-aqueous solvent, is advantageous over traditional aprotic polar organic solvents in electrochemical investigation of electroactive species since it has low vapor pressure, high thermal stability, good conductivity and a wide electrochemical window. [EMIM][N(Tf)₂] shows good solubility in CO₂.

Application

[EMIM][N(Tf)₂] may be used as a green solvent for the synthesis of zinc oxide (ZnO) nanoparticles under microwave conditions. It is useful in reactions which need a solvent with high CO₂ solubility.

Physical form

fluorinated, hydrophobic ionic liquid

Other Notes

Enantioselective reactions in ionic liquids

Legal Information

Product protected by U.S. Patent 5,827,602 assigned to Covalent Associates, Inc. Woburn, Ma, USA

Bezpečnostní informace

• pictograms: GHS06
• signalword: Danger
• hcodes: H301
• pcodes: P264 - P270 - P301 + P310 - P405 - P501
• Hazard Classifications: Acute Tox. 3 Oral
• Storage Class: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• wgk_germany: WGK 1
• ppe: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter