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65363

(R)-(−)-α-Methoxy-α-(trifluoromethyl)phenylacetyl chloride

derivatization grade (chiral), LiChropur, ≥99.0%

Synonim(y):

(R)-(−)-MTPA-Cl, Mosher’s acid chloride

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Do Państwa/SKUDostępnośćCena netto
100 mg
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587,00 zł
500 mg
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2390,00 zł

Informacje o tej pozycji

Wzór liniowy:
C6H5C(OCH3)(CF3)COCl
Numer CAS:
Masa cząsteczkowa:
252.62
UNSPSC Code:
23151817
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
3591563
Assay:
≥99.0% (AT), ≥99.0%

587,00 zł


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grade

derivatization grade (chiral)

Quality Segment

product line

ChiraSelect

assay

≥99.0% (AT), ≥99.0%

optical activity

[α]20/D −132±2°, c = 6 in chloroform

optical purity

enantiomeric ratio: ≥99.5:0.5 (GC)

quality

LiChropur

technique(s)

HPLC: suitable

refractive index

n20/D 1.469, n20/D 1.47 (lit.)

bp

213-214 °C (lit.)

density

1.35 g/mL at 25 °C (lit.)

shipped in

wet ice

storage temp.

−20°C

SMILES string

CO[C@](C(Cl)=O)(c1ccccc1)C(F)(F)F

InChI

1S/C10H8ClF3O2/c1-16-9(8(11)15,10(12,13)14)7-5-3-2-4-6-7/h2-6H,1H3/t9-/m0/s1

InChI key

PAORVUMOXXAMPL-VIFPVBQESA-N

General description

(R)-(-)-a-Methoxy-a-(trifluoromethyl)phenylacetyl chloride (Mosher′s acid chloride) is generally used as a chiral derivatizing agent. It is easily available in enantiomerically pure form. It can form diastereomers with both alcohols and amines.

Application

It was used for derivatizing D-arabinitol and L-arabinitol samples for high performance thin layer chromatography (HPTLC) analysis for studying resolution of the diastereoisomer.
Ready-to-use reagent for the determination of the enantiomeric purity of alcohols and amines after derivatization; doi:10.1038/nprot.2007.354[1]

Packaging

Bottomless glass bottle. Contents are inside inserted fused cone.

Other Notes

Discover LiChropur reagents ideal for HPLC or LC-MS analysis
Please note that R(-)-MTPA-Cl is derived from S(-)-MTPA

Legal Information

ChiraSelect is a trademark of Sigma-Aldrich Co. LLC
LiChropur is a trademark of Merck KGaA, Darmstadt, Germany
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Ta pozycja
36967565365318035
assay

≥99.0% (AT)

assay

99%

assay

≥99.0% (AT)

assay

≥99%

Quality Level

100

Quality Level

200

Quality Level

100

Quality Level

200

storage temp.

−20°C

storage temp.

−20°C

storage temp.

−20°C

storage temp.

2-8°C

bp

213-214 °C (lit.)

bp

213-214 °C (lit.)

bp

213-214 °C (lit.)

bp

95-97 °C/0.05 mmHg (lit.)

refractive index

n20/D 1.469, n20/D 1.47 (lit.)

refractive index

n20/D 1.469 (lit.)

refractive index

n20/D 1.469

refractive index

n20/D 1.474 (lit.)

technique(s)

HPLC: suitable

technique(s)

-

technique(s)

HPLC: suitable

technique(s)

-


pictograms

Corrosion

signalword

Danger

hcodes

Hazard Classifications

Skin Corr. 1B

Klasa składowania

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

192.2 °F - closed cup

flash_point_c

89 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter



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Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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