8.18287

Lithium iodide

anhydrous for synthesis

• Synonim(y): Lithium iodide
• Wzór empiryczny (zapis Hilla): ILi
• Numer CAS: 10377-51-2
• Masa cząsteczkowa: 133.85
• UNSPSC Code: 12352302
• EC Index Number: 233-822-5
• NACRES: NA.22
• MDL number: MFCD00011092
• Grade: synthesis grade
• Form: powder
• Solubility: soluble 1640 g/L

Właściwości

• grade: synthesis grade
• Quality Level: 200
• form: powder
• greener alternative product characteristics: Design for Energy Efficiency; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• mp: 450 °C
• solubility: soluble 1640 g/L
• density: 4 g/cm³ at 20 °C
• bulk density: 1000 kg/m³
• greener alternative category: Enabling
• storage temp.: 2-30°C
• SMILES string: [Li+].[I-]
• InChI: 1S/HI.Li/h1H;/q;+1/p-1
• InChI key: HSZCZNFXUDYRKD-UHFFFAOYSA-M

Opis

General description

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Application

Lithium iodide (LiI) can be used as a catalyst to synthesize:

• N-alkyl 2-pyridone derivatives via O- to N-[1,3]-alkyl migration.
• β-mannosides and β-rhamnosides from glycosyl hemiacetals via one-pot chlorination, iodination, and glycosylation reaction.[1]

It can also be used as:

• Solid electrolyte in the synthesis of Vycor glass/LiI composites applicable in the development of solid-state batteries.
• Iodine source to synthesize primary, secondary, and bridgehead tertiary alkyl iodides by PPh₃-catalyzed iododecarboxylation of aliphatic carboxylates.[2]

Analysis Note

Assay (argentometric): ≥ 98.0 %
Water (K. F.): ≤ 0.50 %

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Informacja o środkach bezpieczeństwa

• Klasa składowania: 13 - Non Combustible Solids
• wgk: WGK 1
• flash_point_f: Not applicable
• flash_point_c: Not applicable