8.00894

N-Ethyldiisopropylamine

for synthesis

• Synonim(y): N-Ethyldiisopropylamine, N,N-Diisopropylethylamine
• Wzór liniowy: [(CH₃)₂CH]₂NCH₂CH₃
• Numer CAS: 7087-68-5
• Masa cząsteczkowa: 129.24
• UNSPSC Code: 12352116
• EC Index Number: 230-392-0
• NACRES: NA.22
• MDL number: MFCD00008868
• Assay: ≥98% (GC)
• Grade: synthesis grade
• Bp: 127 °C/1013 hPa
• Vapor pressure: 14 hPa ( 20 °C)

Właściwości

• grade: synthesis grade
• Quality Level: 200
• vapor pressure: 14 hPa ( 20 °C)
• assay: ≥98% (GC)
• form: liquid
• autoignition temp.: 240 °C
• potency: 200-500 mg/kg LD₅₀, oral (Rat)
• expl. lim.: 0.7-6.3 % (v/v)
• dilution: (for synthesis)
• pH: 12.3 (20 °C in H₂O, as an emulsion)
• kinematic viscosity: 0.88 cSt(20 °C)
• bp: 127 °C/1013 hPa
• transition temp: flash point 9.5 °C
• density: 0.76 g/cm³ at 20 °C
• storage temp.: 2-30°C
• SMILES string: N(C(C)C)(C(C)C)CC
• InChI: 1S/C8H19N/c1-6-9(7(2)3)8(4)5/h7-8H,6H2,1-5H3
• InChI key: JGFZNNIVVJXRND-UHFFFAOYSA-N

Opis

General description

N,N-Diisopropylethylamine (DIPEA), also known as Hunig′s base, is a sterically hindered amine. It is a non-nucleophilic base commonly employed in substitution reactions, alkylations, amide couplings, etc. DIPEA is also used as a base in the Pd-catalyzed cross-coupling reactions, which include Heck coupling and Sonagashira coupling reactions.

Application

• Dual Stimuli-Responsive Hybrid Polymeric Nanoparticles Self-Assembled from POSS-Based: Describes the synthesis of hybrid polymeric nanoparticles using N-Ethyldiisopropylamine in the assembly process (Yang et al., 2022).
• Magnetical Control of the Charge-Separated State Lifetime Realized by Covalent Attachment of a Platinum Complex: Details the use of N-Ethyldiisopropylamine in the preparation of magnetically controllable platinum complexes (Kozaki et al., 2021).
• Hybrid block copolymers of polyesters/polycarbonates and polypeptides synthesized via one-pot sequential ring-opening polymerization: Explains the initiation of polymerization with N-Ethyldiisopropylamine for creating hybrid block copolymers (Gradišar et al., 2018).

Analysis Note

Assay (GC, area%): ≥ 98.0 % (a/a)
Density (d 20 °C/ 4 °C): 0.755 - 0.758
Water (K. F.): ≤ 0.20 %
Identity (IR): passes test

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Informacja o środkach bezpieczeństwa

• signalword: Danger
• pcodes: P210 - P273 - P280 - P301 + P312 - P304 + P340 + P311 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Flam. Liq. 2 - STOT SE 3
• target_organs: Respiratory system
• Klasa składowania: 3 - Flammable liquids
• wgk: WGK 2
• flash_point_f: 49.1 °F
• flash_point_c: 9.5 °C
• pictograms: GHS02,GHS06,GHS05,GHS09
• hcodes: H225,H302,H318,H331,H335,H411