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Sigma-Aldrich

Tris(4,7-diphenyl-1,10-phenanthroline)ruthenium(II) dichloride complex

for fluorescence

Synonim(y):

Ru(ddp)

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About This Item

Wzór empiryczny (zapis Hilla):
C72H48Cl2N6Ru
Numer CAS:
36309-88-3
Masa cząsteczkowa:
1169.17
Numer MDL:
MFCD03095387
Kod UNSPSC:
12352103
Identyfikator substancji w PubChem:
329767411

klasa czystości

for fluorescence

Próba

≥95% (HPCE)

Postać

powder

rozpuszczalność

DMF: soluble
chloroform: soluble
ethanol: soluble
methanol: soluble

fluorescencja

λex 455 nm; λem 610-630 nm in 0.1 M phosphate pH 7.0

ciąg SMILES

Cl[Ru]Cl.c1ccc(cc1)-c2ccnc3c2ccc4c(ccnc34)-c5ccccc5.c6ccc(cc6)-c7ccnc8c7ccc9c(ccnc89)-c%10ccccc%10.c%11ccc(cc%11)-c%12ccnc%13c%12ccc%14c(ccnc%13%14)-c%15ccccc%15

InChI

1S/3C24H16N2.2ClH.Ru/c3*1-3-7-17(8-4-1)19-13-15-25-23-21(19)11-12-22-20(14-16-26-24(22)23)18-9-5-2-6-10-18;;;/h3*1-16H;2*1H;/q;;;;;+2/p-2

Klucz InChI

SKZWFYFFTOHWQP-UHFFFAOYSA-L

Zastosowanie

Ruthenium-tris(4,7-diphenyl-1,10-phenanthroline) dichloride (Ru(dpp)) has been widely used as a probe for luminescent detection and quantitation of oxygen. The fluorescence of the dye (abs. λmax 455 nm, luminescence λmax 613 nm) is strongly reduced by molecular oxygen due to dynamic quenching, making Ru(dpp) a viable oxygen probe based on either measurement of intensity or decay time. Ru(ddp) has been used for fiber optic sensors, studies on oxygen in skin and skin tumors, measurement of oxygen flux through skin, and for oxygen imaging.

Opakowanie

Bottomless glass bottle. Contents are inside inserted fused cone.
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Kod klasy składowania

13 - Non Combustible Solids

Klasa zagrożenia wodnego (WGK)

WGK 3

Temperatura zapłonu (°F)

Not applicable

Temperatura zapłonu (°C)

Not applicable

Środki ochrony indywidualnej

Eyeshields, Gloves, type N95 (US)

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Certyfikaty analizy (CoA)

Lot/Batch Number
BCBL7153V
BCBK0075V
BCBH6868V
BCBD3206V
BCBB4337V

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Dokumenty związane z niedawno zakupionymi produktami zostały zamieszczone w Bibliotece dokumentów.

Odwiedź Bibliotekę dokumentów

G. Liebsch et al.
Appl. Spectroscopy, 54, 548-548 (2000)
W L Rumsey et al.
Science (New York, N.Y.), 241(4873), 1649-1651 (1988-09-23)
The imaging of phosphorescence provides a method for monitoring oxygen distribution within the vascular system of intact tissues. Isolated rat lives were perfused through the portal vein with media containing palladium coproporphyrin, which phosphoresced and was used to image the
I. Klimant et al.
Analytical Chemistry, 67, 3160-3160 (1995)
Federica Tonon et al.
Scientific reports, 9(1), 13557-13557 (2019-09-21)
Among the multiple metabolic signals involved in the establishment of the hepatic zonation, oxygen could play a key role. Indeed, depending on hepatocyte position in the hepatic lobule, gene expression and metabolism are differently affected by the oxygen gradient present
Yuta Ando et al.
Advanced healthcare materials, 8(5), e1900001-e1900001 (2019-02-09)
Despite its revolutionary success in hematological malignancies, chimeric antigen receptor T (CAR-T) cell therapy faces disappointing clinical results in solid tumors. The poor efficacy has been partially attributed to the lack of understanding in how CAR-T cells function in a
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