If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf
8.20171
Brom
for synthesis
Synonym(e):
Brom
Größe auswählen
| Packungsgröße | SKU | Verfügbarkeit | Preis |
|---|---|---|---|
| 250 mL | Warenkorb auf Verfügbarkeit prüfen | CHF 133.00 | |
| 1 L | Warenkorb auf Verfügbarkeit prüfen | CHF 357.00 |
Über diesen Artikel
vapor pressure
233 hPa ( 20 °C)
Quality Segment
form
liquid
reaction suitability
reagent type: oxidant
kinematic viscosity
0.314 cSt(20 °C)
bp
58.8 °C/1013 hPa
mp
-7.3 °C
solubility
35 g/L
density
3.12 g/cm3 at 20 °C (liquid)
storage temp.
15-25°C
SMILES string
[Br-]
InChI
1S/BrH/h1H/p-1
InChI key
CPELXLSAUQHCOX-UHFFFAOYSA-M
General description
Application
- Primäre Alkohole zu Aldehyden oder zu Estern und sekundäre Alkohole zu Ketonen.
- Alkohole oder Diole zu Tetrahydrofuranen in Gegenwart von Silber(I)-Salzen.
- Endiol-bis-trimethylsilylether zu α-Diketonen.
- Aldehyde zu Estern in Gegenwart von alkoholischen Lösungsmitteln und Natriumbicarbonat-Puffer.
- Aliphatische und aromatische Thiole zu Disulfiden.
Brom kann außerdem zusammen mit anderen Reaktionspartnern wie Hexamethylphosphortriamid (HMPA) und Bis(tributylzinn)oxid (HBD) für die selektive Oxidation von sekundären Alkoholen eingesetzt werden. Brom/Nickel-Carboxylate wandeln jedoch 1,4-Diole zu γ-Butyrolactonen durch selektive Oxidation des primären Alkohols um.
Analysis Note
1 of 1
Dieser Artikel | |||
|---|---|---|---|
| solubility 35 g/L | solubility 35 g/L | solubility - | solubility 35 g/L |
| reaction suitability reagent type: oxidant | reaction suitability - | reaction suitability - | reaction suitability - |
| Quality Level 200 | Quality Level 300 | Quality Level 200 | Quality Level 200 |
| form liquid | form liquid | form liquid | form liquid |
| mp -7.3 °C | mp -7.3 °C | mp −7.2 °C (lit.) | mp -7.3 °C |
| bp 58.8 °C/1013 hPa | bp 58.8 °C/1013 hPa | bp 58.8 °C (lit.) | bp 58.8 °C/1013 hPa |
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signalword
Danger
Hazard Classifications
Acute Tox. 1 Inhalation - Aquatic Acute 1 - Eye Dam. 1 - Skin Corr. 1A
wgk
WGK 2
flash_point_f
Not applicable
flash_point_c
Not applicable
hcodes
Lagerklasse
6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
Analysenzertifikate (COA)
Suchen Sie nach Analysenzertifikate (COA), indem Sie die Lot-/Chargennummer des Produkts eingeben. Lot- und Chargennummern sind auf dem Produktetikett hinter den Wörtern ‘Lot’ oder ‘Batch’ (Lot oder Charge) zu finden.
Besitzen Sie dieses Produkt bereits?
In der Dokumentenbibliothek finden Sie die Dokumentation zu den Produkten, die Sie kürzlich erworben haben.
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 8201711000 | 04022536453330 |
| 8201710250 | 04022536453323 |
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How is shipping temperature determined? And how is it related to the product storage temperature?
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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