42215

2,4-Dinitro-phenylhydrazin-phosphorsäure -Lösung

for derivatization (of aldehydes and ketones), LiChropur^™, substitute for the explosive solid, ~0.2 M (~4%)

• Empirische Formel (Hill-System): C₆H₆N₄O₄
• CAS-Nummer: 125038-14-4
• Molekulargewicht: 198.14
• Beilstein: 6258433
• MDL-Nummer: MFCD01863021
• UNSPSC-Code: 41116105
• PubChem Substanz-ID: 329756206
• NACRES: NA.22

Eigenschaften

• Qualität: for derivatization (of aldehydes and ketones); LiChropur^™
• Form: liquid
• Zusammensetzung: 2,4-dinitrophenylhydrazine ; ethanol ; phosphoric acid
• Konzentration: ~0.2 M (~4%)
• Methode(n): thin layer chromatography (TLC): suitable
• Dichte: 1.35 g/mL at 20 °C
• SMILES String: OP(O)(O)=O.NNc1ccc(cc1[N+]([O-])=O)[N+]([O-])=O
• InChI: 1S/C6H6N4O4.H3O4P/c7-8-5-2-1-4(9(11)12)3-6(5)10(13)14;1-5(2,3)4/h1-3,8H,7H2;(H3,1,2,3,4)
• InChIKey: RYSWHUOYGUCXQB-UHFFFAOYSA-N

Beschreibung

Anwendung

• Visible-light excitable Eu(3+)-induced hyaluronic acid-chitosan aggregates with heterocyclic ligands for sensitive and fast recognition of hazardous ions: Utilizes 1,10-phenanthroline monohydrate in environmental sensing applications to detect hazardous ions efficiently (Aleem AR, Ding W, Liu J, Li T, Guo Y, Wang Q, Wang Y, Rehman FUL, Kipper MJ, Belfiore LA, Tang J, 2021).


• Structural diversity of copper(I) complexes formed by pyrrole- and dipyrrolylmethane-based diphosphine ligands with cu-X···HN hydrogen bonds: Researches the coordination chemistry of 1,10-phenanthroline monohydrate, highlighting its role in forming novel copper(I) complexes (Kumar S, Mani G, Dutta D, Mishra S, 2014).


• Direct electron transfer from glucose oxidase immobilized on polyphenanthroline-modified glassy carbon electrode: Demonstrates the use of 1,10-phenanthroline monohydrate in biosensor applications for direct electron transfer mechanisms (Oztekin Y, Ramanaviciene A, Yazicigil Z, Solak AO, Ramanavicius A, 2011).

Sonstige Hinweise

Reagens zum Derivatisieren von Aldehyden und Ketonen, Ersatz für den explosiven Feststoff

Rechtliche Hinweise

LiChropur is a trademark of Merck KGaA, Darmstadt, Germany

Sicherheitshinweise

• Piktogramme: GHS02,GHS05,GHS07
• Signalwort: Danger
• H-Sätze: H226,H290,H302,H314
• P-Sätze: P210 - P233 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338
• Gefahreneinstufungen: Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 3 - Met. Corr. 1 - Skin Corr. 1B
• Lagerklassenschlüssel: 3 - Flammable liquids
• WGK: WGK 3
• Flammpunkt (°F): 86.0 °F
• Flammpunkt (°C): 30 °C
• Persönliche Schutzausrüstung: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter