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Merck

89595

Supelco

Chlorotrimethylsilan

for GC derivatization, LiChropur, ≥99.0% (GC)

Synonym(e):

TMCS, Trimethylchlorsilan, Trimethylsilylchlorid

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About This Item

Lineare Formel:
(CH3)3SiCl
CAS-Nummer:
Molekulargewicht:
108.64
Beilstein:
1209232
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
12000000
PubChem Substanz-ID:
NACRES:
NA.22

Qualität

for GC derivatization
LiChropur

Qualitätsniveau

Dampfdichte

3.7 (vs air)

Dampfdruck

100 mmHg ( 25 °C)

Assay

≥99.0% (GC)

Form

liquid

Selbstzündungstemp.

752 °F

Expl.-Gr.

6.4 %

Eignung der Reaktion

reagent type: derivatization reagent
reaction type: Silylations

Methode(n)

gas chromatography (GC): suitable

Brechungsindex

n20/D 1.387 (lit.)

bp

57 °C (lit.)

mp (Schmelzpunkt)

−40 °C (lit.)

Dichte

0.856 g/mL at 25 °C (lit.)

SMILES String

C[Si](C)(C)Cl

InChI

1S/C3H9ClSi/c1-5(2,3)4/h1-3H3

InChIKey

IJOOHPMOJXWVHK-UHFFFAOYSA-N

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Allgemeine Beschreibung

Chlorotrimethylsilane is a silylation reagent used in the derivatization of triglycerides into volatile fatty esters by gas chromatography (GC).

Anwendung

Learn more in the Product Information

Rechtliche Hinweise

LiChropur is a trademark of Merck KGaA, Darmstadt, Germany

Signalwort

Danger

Gefahreneinstufungen

Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Acute Tox. 4 Dermal - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1A

Zusätzliche Gefahrenhinweise

Lagerklassenschlüssel

3 - Flammable liquids

WGK

WGK 1

Flammpunkt (°F)

-18.4 °F - closed cup

Flammpunkt (°C)

-28 °C - closed cup


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Chlorotrimethylsilane as a reagent for gas chromatographic analysis of fats and oils.
Eras J, et al.
Journal of Chromatography A, 918(1), 227-232 (2001)
Ainara Sistiaga et al.
PloS one, 9(6), e101045-e101045 (2014-06-26)
Neanderthal dietary reconstructions have, to date, been based on indirect evidence and may underestimate the significance of plants as a food source. While zooarchaeological and stable isotope data have conveyed an image of Neanderthals as largely carnivorous, studies on dental
Nil Tandogan et al.
PloS one, 9(6), e101429-e101429 (2014-07-01)
We present an automated method for isolating pure bacterial cultures from samples containing multiple species that exploits the cell's own physiology to perform the separation. Cells compete to reach a chamber containing nutrients via a constriction whose cross-sectional area only
Kathleen A Vermeersch et al.
PloS one, 10(2), e0118262-e0118262 (2015-02-18)
Recently, multicellular spheroids were isolated from a well-established epithelial ovarian cancer cell line, OVCAR-3, and were propagated in vitro. These spheroid-derived cells displayed numerous hallmarks of cancer stem cells, which are chemo- and radioresistant cells thought to be a significant
Zachariah M Norman et al.
ACS nano, 8(7), 7513-7521 (2014-06-25)
We report the evolution of electrical transport and grain size during the sintering of thin films spin-cast from soluble phosphine and amine-bound, chloride-terminated cadmium selenide nanocrystals. Sintering of the nanocrystals occurs in three distinct stages as the annealing temperature is

Artikel

Results of a study involving the ability few Fluka silylating reagents to form GC-MS-compatible trimethylsilylmethyl derivatives of NSAIDs

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