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291056

Methylformiat

anhydrous, 99%

Synonym(e):

Methylformiat

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Über diesen Artikel

Lineare Formel:
HCO2CH3
CAS-Nummer:
Molekulargewicht:
60.05
UNSPSC Code:
12352108
NACRES:
NA.21
PubChem Substance ID:
EC Number:
203-481-7
Beilstein/REAXYS Number:
1734623
MDL number:
Assay:
99%
Grade:
anhydrous
Bp:
32-34 °C (lit.)
Vapor pressure:
32.91 psi ( 55 °C), 9.47 psi ( 20 °C)
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grade

anhydrous

Quality Segment

vapor density

2.1 (vs air)

vapor pressure

32.91 psi ( 55 °C), 9.47 psi ( 20 °C)

assay

99%

form

liquid

autoignition temp.

842 °F

expl. lim.

23 %

impurities

<0.005% water

evapn. residue

<0.0005%

refractive index

n20/D 1.343 (lit.)

pH

4-5 (20 °C, 200 g/L)

bp

32-34 °C (lit.)

mp

−100 °C (lit.)

density

0.974 g/mL at 20 °C (lit.)

SMILES string

[H]C(=O)OC

InChI

1S/C2H4O2/c1-4-2-3/h2H,1H3

InChI key

TZIHFWKZFHZASV-UHFFFAOYSA-N

Application

Methyl formate may be used in the synthesis of the following building blocks:
  • methyl 4-chloro-2-formylbutanoate from methyl 4-chlorobutanoate via -formylation
  • potassium methyl α-[(methoxyethylidene)amino]-β-hydroxyacrylate from methyl α-[(methoxyethylidene)amino]acetate
  • (S)-(-)-1-formyl-2-hydroxymethylpyrrolidine from (S)-(+)-2-hydroxymethylpyrrolidine via N-formylation

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Dieser Artikel
M46837798630259705
grade

anhydrous

grade

reagent grade

grade

ACS reagent, anhydrous

grade

spectrophotometric grade

Quality Level

100

Quality Level

100

Quality Level

200

Quality Level

100

assay

99%

assay

97%

assay

≥99%

assay

≥98%

form

liquid

form

liquid

form

powder

form

liquid

autoignition temp.

842 °F

autoignition temp.

842 °F

autoignition temp.

-

autoignition temp.

842 °F

vapor density

2.1 (vs air)

vapor density

2.1 (vs air)

vapor density

-

vapor density

2.1 (vs air)


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signalword

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Irrit. 2 - Flam. Liq. 1 - STOT SE 1 - STOT SE 3

target_organs

Respiratory system

Lagerklasse

3 - Flammable liquids

wgk

WGK 2

flash_point_f

-2.2 °F - closed cup

flash_point_c

-19 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves



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Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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