20370

tert.-Butylnitrit

technical, ≥90% (GC)

• Synonym(e): 1,1-Dimethylethyl nitrite
• Lineare Formel: (CH₃)₃CONO
• CAS-Nummer: 540-80-7
• Molekulargewicht: 103.12
• Beilstein: 1209339
• EG-Nummer: 208-757-0
• MDL-Nummer: MFCD00002055
• UNSPSC-Code: 12352100
• PubChem Substanz-ID: 329752006
• NACRES: NA.22

Eigenschaften

• Qualität: technical
• Qualitätsniveau: 200
• Assay: ≥90% (GC)
• Form: liquid
• Verunreinigungen: ≤8% tert-butyl alcohol
• Brechungsindex: n20/D 1.368 (lit.); n20/D 1.368
• bp: 61-63 °C (lit.)
• Löslichkeit: alcohol: very soluble; chloroform: very soluble; diethyl ether: very soluble; glycerol: insoluble; water: slightly soluble
• Dichte: 0.864 g/mL at 20 °C; 0.867 g/mL at 25 °C (lit.)
• Lagertemp.: 2-8°C
• SMILES String: CC(C)(C)ON=O
• InChI: 1S/C4H9NO2/c1-4(2,3)7-5-6/h1-3H3
• InChIKey: IOGXOCVLYRDXLW-UHFFFAOYSA-N

Beschreibung

Allgemeine Beschreibung

tert-Butyl nitrite is an organic building block widely used in various organic transformations such as oxidation, diazotization, nitrosation, nitration, oximation, N-synthon, and miscellaneous reactions.

Anwendung

tert-Butyl nitrite can be used as a reactant to synthesize aryl diazonium salts via diazotation.

Sonstige Hinweise

Reagent for nitrosations, kinetics; Clean source of Me₃C radicals by near-UV photolysis

Sicherheitshinweise

• Piktogramme: GHS02,GHS07
• Signalwort: Danger
• H-Sätze: H225,H302 + H332
• P-Sätze: P210 - P233 - P240 - P241 - P301 + P312 - P304 + P340 + P312
• Gefahreneinstufungen: Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Flam. Liq. 2
• Lagerklassenschlüssel: 3 - Flammable liquids
• WGK: WGK 1
• Flammpunkt (°F): 14.0 °F - closed cup
• Flammpunkt (°C): -10 °C - closed cup
• Persönliche Schutzausrüstung: Eyeshields, Faceshields, Gloves