936685

Grubbs-Katalysator^® M102

solid

• Synonym(e): Grubbs Catalyst^® M102, Benzylidene-bis(tricyclohexylphosphine)dichlororuthenium, Bis(tricyclohexylphosphine)benzylidine ruthenium(IV) dichloride ChemBeads, Dichloro(benzylidene)bis(tricyclohexylphosphine)ruthenium(II) ChemBeads, Grubbs Catalyst^® 1st Generation ChemBeads, Grubbs Catalyst^® M1a (C823) ChemBeads
• Empirische Formel (Hill-System): C₄₃H₇₂Cl₂P₂Ru
• CAS-Nummer: 172222-30-9
• Molekulargewicht: 822.96
• MDL number: MFCD01074452
• UNSPSC Code: 12352103
• NACRES: NA.21
• Form: solid ()

Eigenschaften

• Produktname: Grubbs-Katalysator^® M102,
• Quality Segment: 100
• product line: ChemBeads
• form: solid ()
• composition: 4-6 wt% loading of catalyst
• reaction suitability: reagent type: catalyst; core: ruthenium; reaction type: Ring-Opening Polymerization
• greener alternative product characteristics: Waste Prevention; Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• mp: 153 °C (dec.)
• greener alternative category: Aligned
• SMILES string: Cl[Ru]([P](C1CCCCC1)(C2CCCCC2)C3CCCCC3)([P](C4CCCCC4)(C5CCCCC5)C6CCCCC6)(Cl)=CC7=CC=CC=C7, C[Ph].P(C1CCCCC1)(C2CCCCC2)C3CCCCC3.P(C4CCCCC4)(C5CCCCC5)C6CCCCC6.Cl.Cl.[Ru]
• InChI: 1S/2C18H33P.C7H6.2ClH.Ru/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-7-5-3-2-4-6-7;;;/h2*16-18H,1-15H2;1-6H;2*1H;
• InChI key: AULHKSXXVKDNBT-UHFFFAOYSA-N

Beschreibung

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of the 12 Principles of Greener Chemistry. ChemBeads are advanced solid-coated beads for high-throughput experimentation in various chemical applications. They enable precise dispensing of solid reagents, allowing researchers to conduct reactions with minimal material use, thus supporting waste prevention and catalysis principles while ensuring accuracy and reproducibility. This technology enhances efficiency and streamlines experimental processes in chemistry. Click here for more information.

ChemBeads glass beads coated with Grubbs Catalyst^® M102.

Application

First metathesis catalyst to be widely used in organic synthesis. Useful for acyclic diene metathesis polymerization (ADMET), Ring-Opening Metathesis Polymerization (ROMP) of strained cyclic olefins, ring opening metathesis (ROM), olefin cross metathesis (CM) and ring closing metathesis (RCM) of terminal olefins under a variety of reactions conditions.
ChemBeads are chemical coated glass beads. ChemBeads offer improved flowability and chemical uniformity perfect for automated solid dispensing and high-throughput experimentation. The method of creating ChemBeads uses no other chemicals or surfactants allowing the user to accurately dispense sub-milligram amounts of chemical.
For larger scale uses, product also available in powdered form (579726)

Features and Benefits

Grubbs Catalyst® Technology for Olefin Metathesis by Aldrich
High-Throughput Reaction Screening with Nanomoles of Solid Reagents Coated on Glass Beads
Versatile Methods to Dispense Sub-Milligram Quantities of Solids using Chemical Coated Beads for High-Throughput Experimentation
ChemBead Enabled High-Throughput Cross-Electrophile Coupling Reveals a New Complementary Ligand

Legal Information

Grubbs Catalyst 7578

Grubbs Catalyst is a registered trademark of Umicore AG & Co. KG

Sicherheitshinweise

• pictograms: GHS02
• signalword: Warning
• hcodes: H228
• pcodes: P210 - P240 - P241 - P280 - P370 + P378
• Hazard Classifications: Flam. Sol. 2
• Lagerklasse: 4.1B - Flammable solid hazardous materials
• wgk: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable