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86833

Sigma-Aldrich

Tetrabutylammoniumphosphat monobasisch

puriss., 99% (T)

Synonym(e):

Tetrabutylammoniumdihydrogenphosphat

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About This Item

Lineare Formel:
(CH3CH2CH2CH2)4N[OP(OH)2O]
CAS-Nummer:
Molekulargewicht:
339.45
Beilstein:
5196532
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
12352116
PubChem Substanz-ID:
NACRES:
NA.21
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Qualität

puriss.

Qualitätsniveau

Assay

99% (T)

Form

powder

mp (Schmelzpunkt)

151-154 °C (lit.)

SMILES String

OP(O)([O-])=O.CCCC[N+](CCCC)(CCCC)CCCC

InChI

1S/C16H36N.H3O4P/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;1-5(2,3)4/h5-16H2,1-4H3;(H3,1,2,3,4)/q+1;/p-1

InChIKey

ARRNBPCNZJXHRJ-UHFFFAOYSA-M

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Allgemeine Beschreibung

Tetrabutylammoniumphosphat monobasisch ist ein synthetisches Reagenz. Es kann als pH-Puffer in verschiedenen chemischen und biologischen Anwendungen verwendet werden.[1][2]

Anwendung

Tetrabutylammoniumphosphat monobasisch ist als Reagens für folgende Untersuchungen geeignet:
  • Auflösung der Umkehrphasen-Ionenpaar-HPLC (RPIP-HPLC) von Disacchariden[3]
  • Analyse der Disaccharide von 35S-Heparansulfat (HS)[4]
  • Faltungspuffer für die Auflösung von entsalzten Oligonukleotiden[5]
Kann als Reagens für die Analyse von Tetrasacchariden und 35S-Disacchariden mit HPLC verwendet werden.[6] Es kann auch zur Herstellung von mit monobasischem Tetrabutylammoniumphosphat (TBAP) geprägten Polymeren eingesetzt werden.[7]

Lagerklassenschlüssel

11 - Combustible Solids

WGK

WGK 3

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable

Persönliche Schutzausrüstung

Eyeshields, Gloves, type N95 (US)


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Die Dokumentenbibliothek aufrufen

Vaibhav Tiwari et al.
Journal of virology, 80(18), 8970-8980 (2006-08-31)
Herpes simplex virus type 1 (HSV-1) infection of the corneal stroma remains a major cause of blindness. Primary cultures of corneal fibroblasts (CF) were tested and found susceptible to HSV-1 entry, which was confirmed by deconvolution imaging of infected cells.
Polymerisable squaramide receptors for anion binding and sensing.
Manesiotis P, et al.
Journal of Material Chemistry C, 2(42), 8990-8995 (2014)
Robert D Gray et al.
Nucleic acids research, 36(12), 4191-4203 (2008-06-24)
Cation-induced folding into quadruplex structures for three model human telomeric oligonucleotides, d[AGGG(TTAGGG)(3)], d[TTGGG(TTAGGG)(3)A] and d[TTGGG(TTAGGG)(3)], was characterized by equilibrium titrations with KCl and NaCl and by multiwavelength stopped flow kinetics. Cation binding was cooperative with Hill coefficients of 1.5-2.2 in
J Liu et al.
The Journal of biological chemistry, 274(53), 38155-38162 (1999-12-23)
3-O-Sulfation of glucosamine by heparan sulfate D-glucosaminyl 3-O-sulfotransferase (3-OST-1) is the key modification in anticoagulant heparan sulfate synthesis. However, the heparan sulfates modified by 3-OST-2 and 3-OST-3A, isoforms of 3-OST-1, do not have anticoagulant activity, although these isoforms transfer sulfate
Guoqing Xia et al.
The Journal of biological chemistry, 277(40), 37912-37919 (2002-07-26)
Heparan sulfate 3-O-sulfotransferase transfers sulfate to the 3-OH position of a glucosamine residue of heparan sulfate (HS) to form 3-O-sulfated HS. The 3-O-sulfated glucosamine residue contributes to two important biological functions of HS: binding to antithrombin and thereby carrying anticoagulant

Questions

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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