15575

9-Borabicyclo[3.3.1]nonyl-trifluormethansulfonat -Lösung

purum, ~0.5 M in hexane

• Synonym(e): 9-BBN-triflat
• Empirische Formel (Hill-System): C₉H₁₄BF₃O₃S
• CAS-Nummer: 62731-43-5
• Molekulargewicht: 270.08
• PubChem Substance ID: 24849562
• UNSPSC Code: 12352000
• Beilstein/REAXYS Number: 995656
• MDL number: MFCD00167981

Eigenschaften

• grade: purum
• reaction suitability: reagent type: reductant
• concentration: ~0.5 M in hexane
• SMILES string: FC(F)(F)S(=O)(=O)OB1C2CCCC1CCC2
• InChI: 1S/C9H14BF3O3S/c11-9(12,13)17(14,15)16-10-7-3-1-4-8(10)6-2-5-7/h7-8H,1-6H2/t7-,8+
• InChI key: NXHUKDCGEGEZCX-OCAPTIKFSA-N

Beschreibung

Application

Reactant for:

• Preparation of a dialkylborenium ion stabilized by an N-heterocyclic carbene
• Mukaiyama aldol addition
• Preparation of porphyrin dimethyldioxanyl tolyl derivative complex
• Preparation of palladium porphyrin complexes
• Boron-mediated β-alkoxy Me ketone aldol addition reactions

• Enolization agent

Other Notes

Reagent used for the formation of enol borinates from carbonyl compounds employed in stereoselective aldol reactions