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15263

Bis(triphenylphosphoranyliden)ammoniumchlorid

Selectophore

Synonym(e):

Hexaphenyldiphosphazenium-chlorid, PPNCl

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Über diesen Artikel

Lineare Formel:
(C6H5)3P=N(Cl)=P(C6H5)3
CAS-Nummer:
Molekulargewicht:
574.03
UNSPSC Code:
26111700
NACRES:
NB.61
PubChem Substance ID:
EC Number:
244-170-6
Beilstein/REAXYS Number:
4097979
MDL number:


product line

Selectophore

Quality Segment

mp

270-272 °C (lit.), 274-276 °C

storage temp.

2-8°C

SMILES string

ClP(N=P(c1ccccc1)(c2ccccc2)c3ccccc3)(c4ccccc4)(c5ccccc5)c6ccccc6

InChI

1S/C36H30ClNP2/c37-40(34-25-13-4-14-26-34,35-27-15-5-16-28-35,36-29-17-6-18-30-36)38-39(31-19-7-1-8-20-31,32-21-9-2-10-22-32)33-23-11-3-12-24-33/h1-30H

InChI key

QMTYWEYUVVWPQL-UHFFFAOYSA-N

General description

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Application

Bis(triphenylphosphoranylidene)ammonium chloride was used in two-phase titration and electrochemistry, done for physiochemical characterization of sildenafil. It was also used in cyclic voltammetry reactions, used to study ion transfer (IT) and electron transfer (ET), at a liquid-liquid interface supported on a metallic electrode.

Legal Information

Selectophore is a trademark of Merck KGaA, Darmstadt, Germany


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Warning

Hazard Classifications

Acute Tox. 4 Inhalation - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Lagerklasse

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves



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Voltammetric determination of extreme standard Gibbs ion transfer energy.
Olaya AJ
Journal of Electroanalytical Chemistry, 644 (1), 60-66 (2010)
G Werner et al.
Talanta, 36(9), 966-968 (1989-09-01)
A nitrate-sensitive electrode based on the ionic associates between bis(triphenylphosphine)iminium and nitrate ions in nitrobenzene solution is proposed. The electrode can be used for determinations of 10(-5) 0.1M nitrate in aqueous solutions.
Physicochemical characterization of sildenafil: ionization, lipophilicity behavior, and ionic-partition diagram studied by two-phase titration and electrochemistry.
Giraulta HH
Helvetica Chimica Acta, 83, 1465-1465 (2000)



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