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Merck

08748

Sigma-Aldrich

Triethylsulfonium-bis-(trifluormethylsulfonyl)-imid

for electrochemistry, ≥95.0% (qNMR)

Synonym(e):

[SEt3] NTf2

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About This Item

Empirische Formel (Hill-System):
C8H15F6NO4S3
CAS-Nummer:
Molekulargewicht:
399.39
MDL-Nummer:
UNSPSC-Code:
12352100
PubChem Substanz-ID:
NACRES:
NA.22

Qualität

for electrochemistry

Qualitätsniveau

Assay

≥95.0% (qNMR)

Form

liquid

Verunreinigungen

≤200 ppm water

Leitfähigkeit

~6.0 mS/cm

mp (Schmelzpunkt)

-35.5 °C

Anionenspuren

bromide (Br-): ≤10 mg/kg
chloride (Cl-): ≤10 mg/kg
fluoride (F-): ≤10 mg/kg
nitrate (NO3-): ≤10 mg/kg

SMILES String

CC[S+](CC)CC.FC(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F

InChI

1S/C6H15S.C2F6NO4S2/c1-4-7(5-2)6-3;3-1(4,5)14(10,11)9-15(12,13)2(6,7)8/h4-6H2,1-3H3;/q+1;-1

InChIKey

BLODSRKENWXTLO-UHFFFAOYSA-N

Allgemeine Beschreibung

Symmetric and aliphatic trialkylsulfonium cations form room temperature molten salts with bis(trifluoromethylsulfonyl)imide.

Anwendung

Triethylsulfonium bis(trifluoromethylsulfonyl)imide is a room-temperature ionic liquid (RTIL ) that can be used:
  • As an electrolyte in electrochemical double-layer supercapacitors.
  • As a model ionic liquid used in the studies of structure effect of ions on electrochemical windows (EWs).
  • As a component of the gel polymer electrolyte, which is used in the construction of symmetrical electrical-double layer capacitors.
  • As an electrolyte in the in-plane supercapacitor devices.

Piktogramme

Skull and crossbonesCorrosion

Signalwort

Danger

Gefahreneinstufungen

Acute Tox. 3 Oral - Aquatic Chronic 3 - Eye Dam. 1

Lagerklassenschlüssel

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

Persönliche Schutzausrüstung

Eyeshields, Gloves, type ABEK (EN14387) respirator filter


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Die Dokumentenbibliothek aufrufen

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Trigueiro JPC, et al.
Electrochimica Acta, 187(1), 312-322 (2016)
Application of novel room temperature ionic liquids in flexible supercapacitors
Wei Di and Ng TW
Electrochemical Communications, 11(10), 1996-1999 (2009)
Activated graphene oxide/reduced graphene oxide electrodes and low viscous sulfonium cation based ionic liquid incorporated flexible gel polymer electrolyte for high rate supercapacitors
Suleman M, et al.
Journal of alloys and compounds, 695(1), 3376-3392 (2017)
Matsumoto, H., et al.
Chemistry Letters (Jpn), 29, 1430-1430 (2000)
Investigating the electrochemical windows of ionic liquids.
Hayyan M, et al.
Journal of Industrial and Engineering Chemistry, 19(1), 106-112 (2013)

Artikel

Ionic Liquids serve as non-aqueous electrolytes in electrochemical applications, valued for their conductivity and stability.

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