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8.03945

Iron(III) chloride

greener alternative

anhydrous for synthesis

Synonym(e):

Iron(III) chloride, Ferric chloride, Iron trichloride

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PackungsgrößeSKUVerfügbarkeitPreis
500 g
Warenkorb auf Verfügbarkeit prüfen
€ 60,70
1 kg
Warenkorb auf Verfügbarkeit prüfen
€ 78,30
25 kg
Warenkorb auf Verfügbarkeit prüfen
€ 734,00

Über diesen Artikel

Empirische Formel (Hill-System):
Cl3Fe
CAS-Nummer:
Molekulargewicht:
162.20
UNSPSC Code:
12352302
EC Index Number:
231-729-4
NACRES:
NA.22
MDL number:
Grade:
synthesis grade
Form:
powder
Solubility:
920 g/L (Hydrolysis)

€ 60,70


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grade

synthesis grade

Quality Level

vapor pressure

1 hPa ( 20 °C)

form

powder

potency

316 mg/kg LD50, oral (Rat)

greener alternative product characteristics

Catalysis
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sustainability

Greener Alternative Product

pH

1 (20 °C, 200 g/L in H2O)

mp

306 °C (decomposition)

solubility

920 g/L (Hydrolysis)

density

2.89 g/cm3 at 25 °C

bulk density

1000 kg/m3

greener alternative category

storage temp.

2-30°C

SMILES string

[Fe](Cl)(Cl)Cl

InChI

1S/3ClH.Fe/h3*1H;/q;;;+3/p-3

InChI key

RBTARNINKXHZNM-UHFFFAOYSA-K

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Application

Iron(III) chloride (FeCl3) can be used as a catalyst:
  • For the oxidation of glucose to gluconic acid in water.
  • To synthesize 2-iodo substituted benzo[b]thiophenes by iodocyclization of 2-alkynylthioanisoles in the presence of sodium iodide and ethanol as a solvent.
  • In the glycosylation sugars in the presence of allyl and alkynyl alcohols to synthesize corresponding glycosides.
  • To prepare 1,2-trans glycosyl azides by azido glycosylation of glycosyl β-peracetates.[1]

Analysis Note

Assay (iodometric): ≥ 98.0 %
Identity (Fe): passes test
Identity (Cl): passes test

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Dieser Artikel
157740701122710857
form

powder

form

powder

form

powder or crystals

form

solution

solubility

920 g/L (Hydrolysis)

solubility

-

solubility

-

solubility

-

Quality Level

200

Quality Level

200

Quality Level

100

Quality Level

100

grade

synthesis grade

grade

reagent grade

grade

-

grade

-

pH

1 (20 °C, 200 g/L in H2O)

pH

-

pH

-

pH

-

density

2.89 g/cm3 at 25 °C

density

-

density

-

density

0.868 g/mL at 25 °C


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Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Met. Corr. 1 - Skin Irrit. 2 - Skin Sens. 1

flash_point_f

Not applicable

flash_point_c

Not applicable

Lagerklasse

13 - Non Combustible Solids


Zulassungslistungen

Zulassungslistungen werden hauptsächlich für chemische Produkte erstellt. Für nicht-chemische Produkte können hier nur begrenzte Angaben gemacht werden. Kein Eintrag bedeutet, dass keine der Komponenten gelistet ist. Es liegt in der Verantwortung des Benutzers, die sichere und legale Verwendung des Produkts zu gewährleisten.

7718-54-9

CAS No.


Analysenzertifikate (COA)

Suchen Sie nach Analysenzertifikate (COA), indem Sie die Lot-/Chargennummer des Produkts eingeben. Lot- und Chargennummern sind auf dem Produktetikett hinter den Wörtern ‘Lot’ oder ‘Batch’ (Lot oder Charge) zu finden.

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Iron (III) chloride catalyzed glycosylation of peracylated sugars with allyl/alkynyl alcohols
Narayanaperumal S, et al.
Journal of the Brazilian Chemical Society, 23, 1982-1988 (2012)
Green synthesis of benzo [b] thiophenes via iron (III) mediated 5-endo-dig iodocyclization of 2-alkynylthioanisoles
Kesharwani T, et al.
Tetrahedron Letters, 57(3), 411-414 (2016)
Oxidative conversion of glucose to gluconic acid by iron (III) chloride in water under mild conditions
Zhang H, et al.
Green Chemistry, 18(8), 2308-2312 (2016)



Global Trade Item Number

SKUGTIN
803945050004022536383446
803945100004022536383453
803945902504022536680934
803945906004027269030506

Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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