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1.05679

Lithiumchlorid

for analysis EMSURE® ACS,Reag. Ph Eur

Synonym(e):

Lithiumchlorid

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Über diesen Artikel

Empirische Formel (Hill-System):
ClLi
CAS-Nummer:
Molekulargewicht:
42.39
UNSPSC Code:
12352302
EC Index Number:
231-212-3
NACRES:
NA.21
MDL number:
Assay:
≥99% (LiCl basis, silver nitrate titration)
Grade:
ACS reagent
Form:
solid
Solubility:
832 g/L
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grade

ACS reagent

Quality Segment

agency

reag. Ph. Eur.

vapor pressure

1.33 hPa ( 547 °C)

product line

EMSURE®

assay

≥99% (LiCl basis, silver nitrate titration)

form

solid

potency

526 mg/kg LD50, oral (Rat), >2000 mg/kg LD50, skin (Rat)

impurities

≤0.008 meq/g Total of alkali, ≤0.01% Insoluble matter

loss

≤1% loss on drying, 130 °C

pH

6 (20 °C, 50 g/L in H2O)

bp

1360 °C/1013 hPa

mp

614 °C

solubility

832 g/L

density

2.07 g/cm3 at 20 °C

bulk density

530 kg/m3

anion traces

nitrate (NO3-): ≤0.001%, sulfate (SO42-): ≤0.005%

cation traces

Ba: ≤0.002%, Ca: ≤0.005%, Fe: ≤0.0005%, K: ≤0.01%, Mg: ≤0.005%, Na: ≤0.02%, heavy metals (as Pb): ≤0.0005%

storage temp.

2-30°C

SMILES string

[Li+].[Cl-]

InChI

1S/ClH.Li/h1H;/q;+1/p-1

InChI key

KWGKDLIKAYFUFQ-UHFFFAOYSA-M

Application


  • Stereocontrolled synthesis of syn-beta-Hydroxy-alpha-amino acids by direct aldolization of pseudoephenamine glycinamide: Lithiumchlorid wird bei der stereokontrollierten Synthese von Syn-beta-Hydroxy-alpha-Aminosäuren eingesetzt, was seine Rolle in fortschrittlichen Techniken der synthetischen Chemie unterstreicht. Diese Forschungsarbeit bietet Einblicke in die chemische Synthese und die Entwicklung komplexer organischer Verbindungen, die für Chemiker, die sich mit synthetischen Methoden beschäftigen, von Bedeutung sind (Seiple et al., 2014).

Analysis Note

Gehalt (argentometrisch, LiCl): ≥ 99 %
Unlösliche Anteile: ≤ 0,01 %
Nitrat (NO₃): ≤ 0,001 %
Sulfat (SO₄): ≤ 0,005 %
Schwermetalle (als Pb): ≤ 0,0005 %
Ba (Barium): ≤ 0,002 %
Ca (Calcium): ≤ 0,005 %
Fe (Eisen): ≤ 0,0005 %
K (Kalium): ≤ 0,01 %
Mg (Magnesium): ≤ 0.005 %
Na (Natrium): ≤ 0,02 %
Gesamtalkali: ≤ 0,008 meq/g
Trocknungsverlust (130 °C): ≤ 1,0 %

Legal Information

EMSURE is a registered trademark of Merck KGaA, Darmstadt, Germany

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Dieser Artikel
310468213233746460
form

solid

form

crystalline powder, powder, crystals or granules

form

powder, crystals or granules

form

powder

assay

≥99% (LiCl basis, silver nitrate titration)

assay

≥99%

assay

99%

assay

≥99%

solubility

832 g/L

solubility

-

solubility

-

solubility

-

Quality Level

300

Quality Level

200

Quality Level

100

Quality Level

100

grade

ACS reagent

grade

ACS reagent

grade

-

grade

ACS reagent, anhydrous

vapor pressure

1.33 hPa ( 547 °C)

vapor pressure

-

vapor pressure

-

vapor pressure

1.33 hPa ( 547 °C)


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Warning

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2

Lagerklasse

13 - Non Combustible Solids

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable



Analysenzertifikate (COA)

Suchen Sie nach Analysenzertifikate (COA), indem Sie die Lot-/Chargennummer des Produkts eingeben. Lot- und Chargennummern sind auf dem Produktetikett hinter den Wörtern ‘Lot’ oder ‘Batch’ (Lot oder Charge) zu finden.

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Global Trade Item Number

SKUGTIN
W506206-SAMPLE04061837847028
D174203-100ML04061833560594
D174203-25ML04061837018343
W506206-1KG04061837847011
803770025004022536383149
803770000504022536383132
803770100004022536383156
105679901204027269964528
105679010004022536066998
105679025004022536067001
105679905004022536067032

Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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