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Merck

87682

Sigma-Aldrich

Tetramethyl orthosilicate

purum, ≥98.0% (GC)

Sinónimos:

Tetramethoxysilane

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About This Item

Fórmula lineal:
Si(OCH3)4
Número de CAS:
Peso molecular:
152.22
Beilstein/REAXYS Number:
1699658
EC Number:
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.23

vapor density

5.25 (vs air)

Quality Level

vapor pressure

13 hPa ( 20 °C)

grade

purum

assay

≥98.0% (GC)

form

liquid

refractive index

n20/D 1.368 (lit.)
n20/D 1.368

bp

121-122 °C (lit.)

mp

−4 °C (lit.)

density

1.023 g/mL at 25 °C (lit.)

SMILES string

CO[Si](OC)(OC)OC

InChI

1S/C4H12O4Si/c1-5-9(6-2,7-3)8-4/h1-4H3

InChI key

LFQCEHFDDXELDD-UHFFFAOYSA-N

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Application

Used in the sol-gel synthesis of chromium-doped silicates and in the formation of hexagonal mesoporous silica layers.

signalword

Danger

Hazard Classifications

Acute Tox. 1 Inhalation - Eye Dam. 1 - Flam. Liq. 3 - Skin Irrit. 2

Storage Class

3 - Flammable liquids

wgk_germany

WGK 1

flash_point_f

78.8 °F - closed cup

flash_point_c

26 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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Journal of the American Chemical Society, 134(26), 10998-11005 (2012-06-26)
Structure-switching, fluorescence-signaling DNA and RNA aptamers have been reported as highly versatile molecular recognition elements for biosensor development. While structure-switching DNA aptamers have been utilized for solid-phase sensing, equivalent RNA aptamers have yet to be successfully utilized in solid-phase sensors
Yan Fang et al.
Journal of chromatography. A, 1217(41), 6405-6412 (2010-09-03)
A simple capillary flow porometer (CFP) was assembled for through-pore structure characterization of monolithic capillary liquid chromatography columns in their original chromatographic forms. Determination of differential pressures and flow rates through dry and wet short capillary segments provided necessary information
Shota Miyazaki et al.
Journal of chromatography. A, 1218(15), 1988-1994 (2010-12-24)
Chromatographic properties of a new type of monolithic silica rod columns were examined. Silica rod columns employed for the study were prepared from tetramethoxysilane, modified with octadecylsilyl moieties, and encased in a stainless-steel protective column with two polymer layers between
Josef Planeta et al.
Journal of chromatography. A, 1217(36), 5737-5740 (2010-08-03)
The temperature effects during the sol-gel process and ageing of the silica-based monolith on the structure and separation efficiency of the capillary columns (100microm i.d., 150mm) for HPLC separations were studied. The tested columns were synthesized from a mixture of
Zian Lin et al.
Chemical communications (Cambridge, England), 47(34), 9675-9677 (2011-07-30)
An inorganic-organic hybrid affinity monolithic column was synthesized by a novel "one-pot" approach. The resulting hybrid affinity monoliths have potential applications in specific recognition and enrichment of glycoproteins.

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