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222380
Allylpalladium(II) chloride dimer
98%, solid
Sinónimos:
Bis((η3-allyl)(chloro)palladium), Di-ο-allyldi-μ-chlorodipalladium, [PdCl(C3H5)]2
Seleccione un Tamaño
| Tamaño de envase | SKU | Disponibilidad | Precio |
|---|---|---|---|
| 500 mg | Póngase en contacto con nuestro Servicio de Atención al Cliente para disponibilidad | 92,60 € | |
| 1 g | Póngase en contacto con nuestro Servicio de Atención al Cliente para disponibilidad | 147,00 € | |
| 5 g | Póngase en contacto con nuestro Servicio de Atención al Cliente para disponibilidad | 669,00 € | |
| 10 g | Póngase en contacto con nuestro Servicio de Atención al Cliente para disponibilidad | 869,00 € |
Acerca de este artículo
92,60 €
Nombre del producto
Allylpalladium(II) chloride dimer, 98%
Quality Level
assay
98%
form
solid
reaction suitability
core: palladium, reaction type: Cross Couplings, reagent type: catalyst
reaction type: C-H Activation
greener alternative product characteristics
Catalysis
Learn more about the Principles of Green Chemistry.
sustainability
Greener Alternative Product
greener alternative category
, Aligned
storage temp.
2-8°C
SMILES string
Cl[Pd]CC=C.Cl[Pd]CC=C
InChI
1S/2C3H5.2ClH.2Pd/c2*1-3-2;;;;/h2*3H,1-2H2;2*1H;;/q;;;;2*+1/p-2
InChI key
TWKVUTXHANJYGH-UHFFFAOYSA-L
General description
Application
- Synthesis of cationic palladium cataysts, used in the microwave-assisted Heck arylation.
- Synthesis of N-heterocyclic carbene-palladium-η3-allyl chloride complexes, which are efficient catalyst for the Suzuki-Miyaura cross-coupling of aryl bromides and activated aryl chlorides.
- Synthesis of 1,4-diallyl-1,2-dihydroisoquinolines.
- As catalyst for greener Buchwald-Hartwig coupling in TPGS-750-M.
On the Way Towards Greener Transition-Metal-Catalyzed Processes as Quantified by E Factors
1 of 1
Este artículo | |||
|---|---|---|---|
| reaction suitability core: palladium, reagent type: catalyst | reaction suitability core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Cross Couplings, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst | reaction suitability core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Cross Couplings, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst | reaction suitability core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Cross Couplings, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst |
| assay 98% | assay ≥98.0% (C, elemental analysis) | assay 97% | assay 95% |
| form solid | form solid | form solid | form solid |
| Quality Level 200 | Quality Level 100 | Quality Level 100 | Quality Level 100 |
| storage temp. 2-8°C | storage temp. 2-8°C | storage temp. 2-8°C | storage temp. - |
| greener alternative product characteristics Catalysis | greener alternative product characteristics Catalysis | greener alternative product characteristics - | greener alternative product characteristics - |
signalword
Warning
hcodes
Hazard Classifications
Skin Irrit. 2
Clase de almacenamiento
11 - Combustible Solids
ppe
dust mask type N95 (US), Eyeshields, Faceshields, Gloves
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Protocolos
TPGS-750-M surfactant enables various reactions in water at room temperature, enhancing efficiency and versatility in synthesis.
Artículos
A variety of palladium-catalyzed cross-coupling reactions can be run under room temperature conditions in water with TPGS- 750-M, using a variety of commercially available palladium complexes and ligands.
Número de artículo de comercio global
| SKU | GTIN |
|---|---|
| 222380-1G | 04061838777942 |
| 222380-5G | 04061833313251 |
| 222380-10G | 04065270986597 |
| 222380-500MG | 04061838777959 |
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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