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Merck

202991

Sigma-Aldrich

Cerium(III) nitrate hexahydrate

99.999% trace metals basis

Szinonimák:

Cerium trinitrate, Cerous nitrate hexahydrate, Nitric acid cerium salt

Bejelentkezésa Szervezeti és Szerződéses árazás megtekintéséhez


About This Item

Lineáris képlet:
Ce(NO3)3 · 6H2O
CAS-szám:
Molekulatömeg:
434.22
EC-szám:
MDL-szám:
UNSPSC kód:
12352302
PubChem Substance ID:
NACRES:
NA.23
Teszt:
99.999% trace metals basis
Forma:
crystals and lumps

Minőségi szint

Teszt

99.999% trace metals basis

Forma

crystals and lumps

reakcióalkalmasság

reagent type: catalyst
core: cerium

szennyeződések

≤15.0 ppm Trace Metal Analysis

SMILES string

[Ce+3].[H]O[H].[H]O[H].[H]O[H].[H]O[H].[H]O[H].[H]O[H].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O

InChI

1S/Ce.3NO3.6H2O/c;3*2-1(3)4;;;;;;/h;;;;6*1H2/q+3;3*-1;;;;;;

Nemzetközi kémiai azonosító kulcs

QQZMWMKOWKGPQY-UHFFFAOYSA-N

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Általános leírás

Cerium (III) nitrate hexahydrate is a widely used source of cerium in materials science. It is a white-to-yellow crystalline salt that is hygroscopic and air-sensitive. It is highly soluble in water, alcohol, and acetone, although solutions can appear slightly hazy. Like many trivalent metal nitrates, cerium (III) nitrate hexahydrate melts at a low temperature (57 °C)and thermally decomposes at low temperatures too, beginning at 190 °C and proceeding rapidly at 280 °C with complete decomposition to cerium oxide at 390-400 °C.

Alkalmazás

Cerium (III) nitrate hexahydrate is widely used as a source of cerium, especially in the synthesis of micro- or nano-structured ceria (cerium oxide). Because of its high solubility and low decomposition temperature, cerium (III) nitrate hexahydrate is an ideal reagent for hydrothermal reactions, sol-gel processing, and co-precipitation and calcination reactions. Our cerium (III) nitrate hexahydrate 99.999% is designed for applications that demand high-purity cerium with low contaminants of other trace metals and rare earth metals. For example, high-purity cerium nitrate is applicable in studies using cerium (III) nitrate hexahydrate used to dope catalysts, such as recent efforts to boost water splitting using Ce-doped layered double hydroxides . It is also applicable in studies using cerium (III)nitrate hexahydrate to build a ceria support for single-atom catalysts, such as nickel-doped ceria for the hydrogenation of acetylene and platinum-doped ceria for carbon monoxide oxidation. Our high-purity cerium (III) nitrate hexahydrate is also in the solid-state synthesis of cerium-doped phosphors like Ca2YHf2Al3O12 where energy transfer from Ce3+ to other rare earth ions plays a major role in the efficiency and breadth of excitations.

Piktogramok

CorrosionEnvironment

Figyelmeztetés

Danger

Figyelmeztető mondatok

Óvintézkedésre vonatkozó mondatok

Veszélyességi osztályok

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1

Tárolási osztály kódja

5.1B - Oxidizing hazardous materials

WGK

WGK 2

Lobbanási pont (F)

Not applicable

Lobbanási pont (C)

Not applicable

Egyéni védőeszköz

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges


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Dokumentumtár megtekintése

John Jones et al.
Science (New York, N.Y.), 353(6295), 150-154 (2016-07-09)
Catalysts based on single atoms of scarce precious metals can lead to more efficient use through enhanced reactivity and selectivity. However, single atoms on catalyst supports can be mobile and aggregate into nanoparticles when heated at elevated temperatures. High temperatures
Huajie Xu et al.
ACS applied materials & interfaces, 10(7), 6336-6345 (2018-02-01)
Developing convenient doping to build highly active oxygen evolution reaction (OER) electrocatalysts is a practical process for solving the energy crisis. Herein, a facile and low-cost in situ self-assembly strategy for preparing a Ce-doped NiFe-LDH nanosheets/nanocarbon (denoted as NiFeCe-LDH/CNT, LDH
Highly efficient near-UV-excitable Ca2YHf2Al3O12:Ce3+,Tb3+ green-emitting garnet phosphors with potential application in high color rendering warm-white LEDs.
Want S, et al.
Journal of Material Chemistry C, 8, 4408-4420 (2020)
Fabrication of layered double hydroxide microcapsules mediated by cerium doping in metal?organic frameworks for boosting water splitting.
Huajie Xu, et al.
Energy & Environmental Science, 13, 2949-2956 (2020)
Christopher Riley et al.
Journal of the American Chemical Society, 140(40), 12964-12973 (2018-09-18)
Since the discovery that ceria is an active catalyst for selective hydrogenation of alkynes, there has been much debate on the catalytic mechanism. In this work, we propose, based on density functional theory (DFT) investigations, a mechanism that involves the

Cikkek

Lanthanide ions in spectral conversion enhance solar cell efficiency via photon conversion.

Rare earth elements are vital in everyday life worldwide: catalysts in cars, colors in screens, magnets in electronics. Essential for modern living.

Tudóscsoportunk valamennyi kutatási területen rendelkezik tapasztalattal, beleértve az élettudományt, az anyagtudományt, a kémiai szintézist, a kromatográfiát, az analitikát és még sok más területet.

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