900421

9-Mesityl-3,6-di-tert-butyl-10-phenylacridinium tetrafluoroborate

≥95%

• Szinonimák: 3,6-Bis(1,1-dimethylethyl)-10-phenyl-9-(2,4,6-trimethylphenyl)-acridinium tetrafluoroborate, 3,6-Di-tert-butyl-9-(2,4,6-trimethylphenyl)-10-phenylacridinium tetrafluoroborate
• Tapasztalati képlet (Hill-képlet): C₃₆H₄₀BF₄N
• CAS-szám: 1810004-87-5
• Molekulatömeg: 573.51
• MDL-szám: MFCD31381908
• UNSPSC kód: 12352005
• NACRES: NA.22

Tulajdonságok

• Minőségi szint: 100
• Teszt: ≥95%
• Forma: powder or crystals
• reakcióalkalmasság: core: acridinium; reagent type: catalyst; reaction type: Photocatalysis
• mp: 277.2 °C
• fotokatalizátor aktiválása: 455 nm
• SMILES string: [F-][B+3]([F-])([F-])[F-].C=1C=CC(=CC1)[N+]=2C=3C=C(C=CC3C(=C4C=CC(=CC42)C(C)(C)C)C=5C(=CC(=CC5C)C)C)C(C)(C)C
• InChI: InChI=1S/C36H40N.BF4/c1-23-19-24(2)33(25(3)20-23)34-29-17-15-26(35(4,5)6)21-31(29)37(28-13-11-10-12-14-28)32-22-27(36(7,8)9)16-18-30(32)34;2-1(3,4)5/h10-22H,1-9H3;/q+1;-1
• Nemzetközi kémiai azonosító kulcs: YUNSHKYOOCWQRB-UHFFFAOYSA-N

Leírás

Alkalmazás

9-Mesityl-3,6-di-tert-butyl-10-phenylacridinium tetrafluoroborate is an acridium-based photocatalyst that can be an alternative to transition-metal-based photocatalysts due to its higher chemical stability and attenuated redox potential.

When employed with TEMPO, this acridinium photocatalyst promotes the site-selective amination of a variety of simple and complex aromatics with heteroaromatic azoles. When ammonium carbamate is used as the amine, anilines can be achieved directly.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Egyéb megjegyzések

Site-selective arene C-H amination via photoredox catalysis

Biztonsági adatok

• Tárolási osztály kódja: 11 - Combustible Solids
• WGK: WGK 3
• Lobbanási pont (F): Not applicable
• Lobbanási pont (C): Not applicable