405868

4′-Chloro-2,2′:6′,2′′-terpyridine

99%

• Wzór empiryczny (zapis Hilla): C₁₅H₁₀ClN₃
• Numer CAS: 128143-89-5
• Masa cząsteczkowa: 267.71
• Numer MDL: MFCD00191930
• Kod UNSPSC: 12352100
• Identyfikator substancji w PubChem: 24865338
• NACRES: NA.22

Właściwości

• Próba: 99%
• wynik ekologicznej alternatywy: old score: 51; new score: 35; Find out more about DOZN™ Scoring
• charakterystyka ekologicznej alternatywy: Waste Prevention; Atom Economy; Less Hazardous Chemical Syntheses; Safer Solvents and Auxiliaries; Use of Renewable Feedstocks; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• mp: 148-150 °C (lit.)
• grupa funkcyjna: chloro
• kategoria ekologicznej alternatywy: Re-engineered,
• ciąg SMILES: Clc1cc(nc(c1)-c2ccccn2)-c3ccccn3
• InChI: 1S/C15H10ClN3/c16-11-9-14(12-5-1-3-7-17-12)19-15(10-11)13-6-2-4-8-18-13/h1-10H
• Klucz InChI: AHEMFMCEBIJRMU-UHFFFAOYSA-N

Opis

Opis ogólny

4′-Chloro-2,2′:6′,2′′-terpyridine (4′-Cltpy, Cltpy, Cl-terpy) is a tridentate ligand that contains a terpyridine (tpy) site with a Cl site at the 4 -position. It coordinates with various metal ions through these two sites to form different coordination polymers.[1] Crystal structure study shows terpyridine unit of Cltpy adopts a trans, trans conformation. Mol­ecules assemble themselves into stacked columns along the b axis, with an inter­planar distance of 3.51Å.[2] It undergoes Williamson type ether reactions with α,ω-bishydroxy-functionalized poly(propylene oxide).[3] It undergoes Williamson type reaction with α-hydroxy-ω-carboxy-functionalized poly(ethylen-oxide) to afford monoterpyridine terminated telechelics.[4]

We are committed to bringing you Greener Alternative Products, which adhere to one of the four categories of Greener Alternatives . This product belongs to category of Re-engineered products, showing key improvements in Green Chemistry Principles “Waste Prevention”, “Atom Economy”, “Less Hazardous Chemical Syntheses”, “Safer Solvents and Auxiliaries” and “Use of Renewable Feedstock”. Click here to view its DOZN scorecard.

Zastosowanie

4′-Chloro-2,2′:6′,2′′-terpyridine may be used in the preparation of the following:

• mono- and bis-terpyridines[5]
• bis-hydroxy-functionalized terpyridine cadmium(II) complex and a fullerene derivative[5]
• 4-functionalized 2,2´:6´,2´´-terpyridines, building blocks for novel supramolecular structures, such as double helicates, dendrimers, micelles and metallo-supramolecular polymers[6]

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Informacja o środkach bezpieczeństwa

• Piktogramy: GHS06,GHS05
• Hasło ostrzegawcze: Danger
• Zwroty wskazujące rodzaj zagrożenia: H301,H315,H318,H335
• Zwroty wskazujące środki ostrożności: P261 - P264 - P280 - P301 + P310 - P302 + P352 - P305 + P351 + P338
• Klasyfikacja zagrożeń: Acute Tox. 3 Oral - Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3
• Organy docelowe: Respiratory system
• Kod klasy składowania: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• Klasa zagrożenia wodnego (WGK): WGK 3
• Temperatura zapłonu (°F): Not applicable
• Temperatura zapłonu (°C): Not applicable
• Środki ochrony indywidualnej: dust mask type N95 (US), Eyeshields, Faceshields, Gloves