Összes fotó(2)
Fontos dokumentumok
901409
[Ir(dF(Me)ppy)2(dtbbpy)]PF6
Szinonimák:
Iridium(III) bis[2-(2,4-difluorophenyl)-5-methylpyridine-N,C20]-4,40-di-tert-butyl-2,20-bipyridine hexafluorophosphate
Bejelentkezésa Szervezeti és Szerződéses árazás megtekintéséhez
Összes fotó(2)
About This Item
Tapasztalati képlet (Hill-képlet):
C42H40F10IrN4P
CAS-szám:
Molekulatömeg:
1013.97
MDL-szám:
UNSPSC kód:
12161600
NACRES:
NA.22
Javasolt termékek
![(Ir[dF(CF3)ppy]2(dtbpy))PF6](/deepweb/assets/sigmaaldrich/product/structures/982/913/02dd8ddd-6deb-40a0-ab9b-07b18f1abb09/640/02dd8ddd-6deb-40a0-ab9b-07b18f1abb09.png)
![[Ir{dFCF3ppy}2(bpy)]PF6](/deepweb/assets/sigmaaldrich/product/structures/180/924/79119ac4-7d62-429d-b23d-a14c012c6050/640/79119ac4-7d62-429d-b23d-a14c012c6050.png)
![[Ir(dtbbpy)(ppy)2]PF6](/deepweb/assets/sigmaaldrich/product/structures/158/329/2544d673-d267-4aa1-8f46-2652aad4bfa0/640/2544d673-d267-4aa1-8f46-2652aad4bfa0.png)
![[Ir(dFCF3ppy)2-(5,5’-dCF3bpy)]PF6 ≥95%](/deepweb/assets/sigmaaldrich/product/structures/422/901/e00f3148-fb86-4f94-9e79-21d064c3f327/640/e00f3148-fb86-4f94-9e79-21d064c3f327.png)
![Ir[dFFppy]2-(4,4′-dCF3bpy)PF6 ≥95%](/deepweb/assets/sigmaaldrich/product/structures/816/772/b116c17c-e6b2-4c95-be64-45a5a851d823/640/b116c17c-e6b2-4c95-be64-45a5a851d823.png)
![[4,4′-Bis(1,1-dimethylethyl)-2,2′-bipyridine] nickel (II) dichloride](/deepweb/assets/sigmaaldrich/product/structures/471/091/6faa29b1-bf8a-4d87-90b2-4cc55e082620/640/6faa29b1-bf8a-4d87-90b2-4cc55e082620.png)
![[Ir(p-F(Me)ppy)2-(4,4′-dtbbpy)]PF6 ≥95%](/deepweb/assets/sigmaaldrich/product/structures/231/079/a5445824-9d4b-4c84-9c5f-f3acbcc75fd4/640/a5445824-9d4b-4c84-9c5f-f3acbcc75fd4.png)
Forma
solid
Minőségi szint
reakcióalkalmasság
core: iridium
reaction type: Photocatalysis
reagent type: catalyst
fotokatalizátor aktiválása
450 nm
Related Categories
Alkalmazás
[Ir(dF(Me)ppy)2(dtbbpy)]PF6 is a photocatalyst readily facilitates hydroamination of olefins as well as the decarboxylative arylation and vinylation of carboxylic acids via metallaphotoredox catalysis.
Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)
Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)
Egyéb megjegyzések
Catalytic intermolecular hydroaminations of unactivated olefins with secondary alkyl amines
Merging photoredox and nickel catalysis: Decarboxylative cross-coupling of carboxylic acids with vinyl halides
Enhanced luminescent iridium(III) complexes bearing aryltriazole cyclometallated ligands
Site-Selective and Stereoselective C-H Alkylations of Carbohydrates via Combined Diarylborinic Acid and Photoredox Catalysis
Merging photoredox and nickel catalysis: Decarboxylative cross-coupling of carboxylic acids with vinyl halides
Enhanced luminescent iridium(III) complexes bearing aryltriazole cyclometallated ligands
Site-Selective and Stereoselective C-H Alkylations of Carbohydrates via Combined Diarylborinic Acid and Photoredox Catalysis
kapcsolódó termék
Product No.
Leírás
Árazás
Tárolási osztály kódja
11 - Combustible Solids
WGK
WGK 3
Lobbanási pont (F)
Not applicable
Lobbanási pont (C)
Not applicable
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Victoria Dimakos et al.
Journal of the American Chemical Society, 141(13), 5149-5153 (2019-03-23)
Diphenylborinic acid serves as a cocatalyst for site- and stereoselective C-H alkylation reactions of carbohydrates under photoredox conditions using quinuclidine as the hydrogen atom transfer mediator. Products arising from selective abstraction of the equatorial hydrogens of cis-1,2-diol moieties, followed by
Andrew J Musacchio et al.
Science (New York, N.Y.), 355(6326), 727-730 (2017-02-18)
The intermolecular hydroamination of unactivated alkenes with simple dialkyl amines remains an unsolved problem in organic synthesis. We report a catalytic protocol for efficient additions of cyclic and acyclic secondary alkyl amines to a wide range of alkyl olefins with
Correlating electronic structures to electrochemiluminescence of cationic Ir complexes.
Swanick KN, et al.
Royal Society of Chemistry Advances, 43, 19961-19964 (2013)
Adam Noble et al.
Journal of the American Chemical Society, 137(2), 624-627 (2014-12-19)
Decarboxylative cross-coupling of alkyl carboxylic acids with vinyl halides has been accomplished through the synergistic merger of photoredox and nickel catalysis. This new methodology has been successfully applied to a variety of α-oxy and α-amino acids, as well as simple
Sébastien Ladouceur et al.
Inorganic chemistry, 50(22), 11514-11526 (2011-10-04)
Herein we report the synthesis of 4-aryl-1-benzyl-1H-1,2,3-triazoles (atl), made via "Click chemistry" and their incorporation as cyclometallating ligands into new heteroleptic iridium(III) complexes containing diimine (N(^)N) ancillary ligands 2,2'-bipyridine (bpy) and 4,4'-di-tert-butyl-2,2'-bipyridine (dtBubpy). Depending on decoration, these complexes emit from
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