763314

sSPhos Pd G2

95%

• Szinonimák: Chloro(sodium-2-dicyclohexylphosphino-2′,6′-dimethoxy-1,1′-biphenyl-3′-sulfonate)[2-(2′-amino-1,1′-biphenyl)]palladium(II)
• Tapasztalati képlet (Hill-képlet): C₃₈H₄₄ClNNaO₅PPdS
• CAS-szám: 2375242-78-5
• Molekulatömeg: 822.66
• MDL-szám: MFCD22377809
• UNSPSC kód: 12161600
• PubChem Substance ID: 329767044
• NACRES: NA.22

Tulajdonságok

• Minőségi szint: 100
• Teszt: 95%
• form: solid
• Jellemzők: generation 2
• reakcióalkalmasság: core: palladium; reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: catalyst; reaction type: Cross Couplings
• mp: 193-194 °C (decomposition)
• funkcionális csoport: phosphine
• SMILES string: [Na+].Nc1ccccc1-c2ccccc2[Pd]Cl.COc3ccc(c(OC)c3-c4ccccc4P(C5CCCCC5)C6CCCCC6)S([O-])(=O)=O
• InChI: 1S/C26H35O5PS.C12H10N.ClH.Na.Pd/c1-30-22-17-18-24(33(27,28)29)26(31-2)25(22)21-15-9-10-16-23(21)32(19-11-5-3-6-12-19)20-13-7-4-8-14-20;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;;;/h9-10,15-20H,3-8,11-14H2,1-2H3,(H,27,28,29);1-6,8-9H,13H2;1H;;/q;;;2*+1/p-2
• Nemzetközi kémiai azonosító kulcs: MWQYWXJKMDRSJN-UHFFFAOYSA-L

Leírás

Alkalmazás

sSPhos Pd G2 can be used as a water-soluble Pd-precatalyst in:

• DNA-compatible Suzuki-Miyaura reaction between DNA-linked aryl halides and various boronic acids/esters including heteroaryl boronates.
• DNA-compatible hydroxycarbonylation reactions.
• The cross-coupling reaction between boronic ester and brominated cyclic nucleotide to synthesize cyclic adenosine and guanosine monophosphate in the presence of potassium phosphate and hydrochloric acid.

Biztonsági adatok

• Tárolási osztály kódja: 11 - Combustible Solids
• WGK: WGK 3
• Lobbanási pont (F): Not applicable
• Lobbanási pont (C): Not applicable