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1,5-Diaminonaphthalene

matrix substance for MALDI-MS, ≥99.0% (HPLC)

Sinonimo/i:

1,5-DAN, 1,5-Naphthalenediamine, NSC 401110

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About This Item

Formula condensata:
C10H6(NH2)2
Numero CAS:
Peso molecolare:
158.20
Beilstein:
907947
Numero CE:
Numero MDL:
Codice UNSPSC:
12000000
ID PubChem:
NACRES:
NA.21

Grado

matrix substance for MALDI-MS

Livello qualitativo

Saggio

≥99.0% (HPLC)

Composizione

carbon content, 75.92% (theory)
hydrogen content, 6.37% (theory)
nitrogen content, 17.71% (theory)

Classi chimiche degli analiti

oligonucleotides, peptides

tecniche

MALDI-MS: suitable

Punto di fusione

185-187 °C (lit.)

Cationi in tracce

Ba: ≤5.0 mg/kg
Ca: ≤20 mg/kg
Cd: ≤5.0 mg/kg
Co: ≤5.0 mg/kg
Cr: ≤5.0 mg/kg
Cu: ≤5.0 mg/kg
K: ≤10 mg/kg
Mg: ≤5.0 mg/kg
Mn: ≤5.0 mg/kg
Na: ≤10 mg/kg
Ni: ≤5.0 mg/kg
Pb: ≤5.0 mg/kg
Zn: ≤5.0 mg/kg

Stringa SMILE

Nc1cccc2c(N)cccc12

InChI

1S/C10H10N2/c11-9-5-1-3-7-8(9)4-2-6-10(7)12/h1-6H,11-12H2
KQSABULTKYLFEV-UHFFFAOYSA-N

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Descrizione generale

1,5-Diaminonaphthalene is used in the production of 1,5-naphthalene diisocyanate and polyurethane elastomers.

Applicazioni

1,5-Diaminonaphthalene is used as an effective matrix in the analysis of IgG protein using top-down and middle-down mass spectrometry with multiple fragmentation techniques such as electron transfer dissociation (ETD) and matrix-assisted laser desorption ionization in-source decay (MALDI-ISD) method.

Confezionamento

Bottomless glass bottle. Contents are inside inserted fused cone.

Risultati analitici

metal trace analysis corresponds to requirements

Prodotti correlati

N° Catalogo
Descrizione
Determinazione del prezzo

Avvertenze

Warning

Indicazioni di pericolo

Classi di pericolo

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 2 - Skin Sens. 1

Codice della classe di stoccaggio

11 - Combustible Solids

Classe di pericolosità dell'acqua (WGK)

WGK 2

Punto d’infiammabilità (°F)

438.8 °F - DIN 51758

Punto d’infiammabilità (°C)

226 °C - DIN 51758


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I clienti hanno visto anche

Daiki Asakawa et al.
Journal of mass spectrometry : JMS, 47(2), 180-187 (2012-02-24)
Matrix-assisted laser desorption/ionization in-source decay (MALDI-ISD) has been used for characterization of a phosphorylated peptides and proteins because labile phosphate group is not lost during the MALDI-ISD process. The conventional MALDI-ISD is initiated by the hydrogen transfer from reducing matrix
Delphine Debois et al.
Analytical chemistry, 82(10), 4036-4045 (2010-04-20)
Matrix-assisted laser desorption ionization-mass spectrometry (MALDI-MS) imaging is a powerful technique giving access to the distribution of a large range of biomolecules directly from a tissue section, allowing, for example, the discovery of new pathological biomarkers. Nevertheless, one main difficulty
Laura Molin et al.
Rapid communications in mass spectrometry : RCM, 25(20), 3091-3096 (2011-09-29)
1,5-Diaminonaphthalene (DAN) has been described as an interesting and effective matrix for matrix-assisted laser desorption/ionization (MALDI) experiments in positive ion mode, being able to activate in-source decomposition phenomena and, when employed for the analysis of proteins containing disulphide bridge(s), being
Aurélien Thomas et al.
Analytical chemistry, 84(4), 2048-2054 (2012-01-17)
Matrix sublimation has demonstrated to be a powerful approach for high-resolution matrix-assisted laser desorption ionization (MALDI) imaging of lipids, providing very homogeneous solvent-free deposition. This work presents a comprehensive study aiming to evaluate current and novel matrix candidates for high
Yuko Fukuyama et al.
Journal of mass spectrometry : JMS, 41(2), 191-201 (2005-12-31)
MS/MS is indispensable for the amino acid sequencing of peptides. However, its use is limited for peptides containing disulfide bonds. We have applied the reducing properties of 1,5-diaminonaphthalene (1,5-DAN) as a MALDI matrix to amino acid sequencing and disulfide bond

Protocolli

A short abstract on a method using QuEChERS and GC/MS/MS for determination of fipronil & fipronil sulfone.

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