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45689

Thiram

PESTANAL®, analytical standard

Synonym(s):

Tetramethylthiuram disulfide, Bis(dimethylthiocarbamoyl) disulfide, Bis(dimethylthiocarbamyl) disulfide, Thiram

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About This Item

Linear Formula:
(CH3)2NCSS2CSN(CH3)2
CAS Number:
Molecular Weight:
240.43
UNSPSC Code:
41116107
NACRES:
NA.24
PubChem Substance ID:
EC Number:
205-286-2
Beilstein/REAXYS Number:
1725821
MDL number:
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grade

analytical standard

Quality Level

product line

PESTANAL®

autoignition temp.

316 °F

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable, gas chromatography (GC): suitable

mp

156-158 °C (lit.)

application(s)

agriculture
cleaning products
cosmetics
environmental
food and beverages
personal care

format

neat

SMILES string

CN(C)C(=S)SSC(=S)N(C)C

InChI

1S/C6H12N2S4/c1-7(2)5(9)11-12-6(10)8(3)4/h1-4H3

InChI key

KUAZQDVKQLNFPE-UHFFFAOYSA-N

General description

Thiram is a dithiocarbamate fungicide with protective action, used for the control of many fungal diseases affecting fruits, vegetables and ornamentals.

Application

Thiram may be used as an analytical reference standard for the quantification of the analyte in fruits and vegetables using different chromatography techniques.
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Other Notes

Ion Mobility: TWCCSN2 value of 152.3 Å2 [M+Na]+

The collision cross section (CCS) measurement was provided by Waters Corporation, using the SYNAPT XS mass spectrometer.
For a description and overview of how ion mobility enables the measurement of the CCS of an ion visit ims.waters.com.
Further information on the SYNAPT XS mass spectrometer can be found on the IMS microsite and product webpage.

TWCCS measurements are expected to be within 2% of this reference value.

P/N 45689 is part of the Waters Extractables & Leachables UNIFI scientific library which can be downloaded from Waters Marketplace.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

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This Item
T242014568832013
application(s)

agriculture
cleaning products
cosmetics
environmental
food and beverages
personal care

application(s)

-

application(s)

agriculture
cleaning products
cosmetics
environmental
food and beverages
personal care

application(s)

agriculture
cleaning products
cosmetics
environmental
food and beverages
personal care

technique(s)

HPLC: suitable, gas chromatography (GC): suitable

technique(s)

-

technique(s)

HPLC: suitable, gas chromatography (GC): suitable

technique(s)

HPLC: suitable, gas chromatography (GC): suitable

format

neat

format

-

format

neat

format

neat

Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

100

grade

analytical standard

grade

-

grade

analytical standard

grade

analytical standard

shelf life

limited shelf life, expiry date on the label

shelf life

-

shelf life

limited shelf life, expiry date on the label

shelf life

limited shelf life, expiry date on the label


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signalword

Warning

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT RE 2 Oral

target_organs

Liver

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves



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Pesticide Residues in Food - 1992: Report of the Joint Meeting of the FAO Panel of Experts on Pesticide Residues in Food and the Environment and the WHO Expert Group on Pesticide Residues, Rome, 21-30 September 1992 (1997)
HPLC-electrochemical detection with graphite-poly (tetrafluoroethylene) electrode determination of the fungicides thiram and disulfiram
Fernandez.C, et al.
Talanta, 43(8), 1341-1348 (1961)
Rapid and simple method for determination of thiram in fruits and vegetables with high-performance liquid chromatography with ultraviolet detection
Ekroth.BS, et al.
Journal of Agricultural and Food Chemistry, 46(12), 5302-5304 (1998)



Global Trade Item Number

SKUGTIN
45689-250MG04061832341767

Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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