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31653

Zinc

greener alternative

ACS reagent grade, ≥99.9%, granular, puriss. p.a., reag. ISO, reag. Ph. Eur.

Synonym(s):

Zn

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About This Item

Linear Formula:
Zn
CAS Number:
Molecular Weight:
65.39
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
11101719
EC Number:
231-175-3
MDL number:
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Product Name

Zinc, puriss. p.a., ACS reagent, reag. ISO, reag. Ph. Eur., ≥99.9%, granular

Quality Level

agency

USP/NF, reag. ISO, reag. Ph. Eur.

vapor pressure

1 mmHg ( 487 °C)

grade

ACS reagent, puriss. p.a.

assay

≥99.9%

form

granular

reaction suitability

core: zinc, reagent type: catalyst

greener alternative product characteristics

Catalysis
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sustainability

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resistivity

5.8 μΩ-cm, 20°C

bp

907 °C (lit.)

mp

420 °C (lit.)

density

7.133 g/mL at 25 °C (lit.)

cation traces

As: ≤0.1 mg/kg, Cd: ≤5 mg/kg, Cu: ≤10 mg/kg, Fe: ≤20 mg/kg, Pb: ≤50 mg/kg, Sn: ≤10 mg/kg

greener alternative category

SMILES string

[Zn]

InChI

1S/Zn

InChI key

HCHKCACWOHOZIP-UHFFFAOYSA-N

General description

We are committed to bringing you Greener Alternative Products, which adhere to one of the four categories of Greener Alternatives. This product falls under category 12 PAP and aligns with the Green Chemistry Principle of Catalysis. Click here for more information.

Application

Zinc can be used in the preparation of organozinc reagents, Reformatsky reagents, and the Simmons-Smith reagent.

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This Item
243469266353565148
reaction suitability

core: zinc, reagent type: catalyst

reaction suitability

core: zinc, reagent type: catalyst

reaction suitability

core: zinc, reagent type: catalyst

reaction suitability

core: zinc, reagent type: catalyst

assay

≥99.9%

assay

≥99.8%

assay

99.9% trace metals basis

assay

99%

form

granular

form

granular

form

pieces

form

granular

Quality Level

200

Quality Level

200

Quality Level

100

Quality Level

100

mp

420 °C (lit.)

mp

420 °C (lit.)

mp

420 °C (lit.)

mp

420 °C (lit.)

density

7.133 g/mL at 25 °C (lit.)

density

7.133 g/mL at 25 °C (lit.)

density

7.133 g/mL at 25 °C (lit.)

density

7.133 g/mL at 25 °C (lit.)


Storage Class

11 - Combustible Solids

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)



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A scalable zinc activation procedure using dibal-h in a reformatsky reaction.
Girgis M J
Organic Process Research & Development, 13(6), 1094-1099 (2009)
Use of activation methods for organozinc reagents.
Erdik E
Tetrahedron, 43(10), 2203-2212 (1987)
Highly efficient, general procedure for the preparation of alkylzinc reagents from unactivated alkyl bromides and chlorides.
Huo S
Organic Letters, 5(4), 423-425 (2003)



Global Trade Item Number

SKUGTIN
31653-6X1KG04061833546529
31653-6X250G04061826690895
31653-1KG04061835554997
31653-250G04061835555000

Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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