D2757

2,3-Diaminonaphthalene

≥95% purity (HPLC), powder

• Synonym(s): 2,3-Naphthalenediamine, DAN
• Empirical Formula (Hill Notation): C₁₀H₁₀N₂
• CAS Number: 771-97-1
• Molecular Weight: 158.20
• NACRES: NA.47
• PubChem Substance ID: 24893709
• UNSPSC Code: 12171500
• EC Number: 212-241-0
• MDL number: MFCD00004116
• Beilstein/REAXYS Number: 2206394

Properties

• Product Name: 2,3-Diaminonaphthalene, ≥95% (HPLC), powder
• Quality Level: 100
• assay: ≥95% (HPLC)
• form: powder
• technique(s): titration: suitable
• color: off-white to dark beige, to Dark Brown
• mp: 198-200 °C
• solubility: pyridine: 50 mg/mL
• application(s): diagnostic assay manufacturing; hematology; histology
• storage temp.: room temp
• SMILES string: Nc1cc2ccccc2cc1N
• InChI: 1S/C10H10N2/c11-9-5-7-3-1-2-4-8(7)6-10(9)12/h1-6H,11-12H2
• InChI key: XTBLDMQMUSHDEN-UHFFFAOYSA-N

Description

General description

2,3-Diaminonaphthalene is also known as 2,3-Naphthalenediamine or DAN. It is one of the isomers of naphthalene bearing two amino groups, which are also called naphthalenediamines. They are usually prepared by reducing the nitronaphthalene derivative and aminating the subsequent hydroxynaphthalene derivative.

Application

• 2,3-Diaminonaphthalene (DAN) has been used for the fluorometric measurement of nitrite/nitrate.
• DAN has been used to develop a solid phase extraction-multisyringe flow injection system to spectrophotometrically detect the presence of selenium.
• It has been employed in a study to develop a colorimetric assay for the detection of methylglyoxal.
• It has also been used in a study to develop a novel ratiometric fluorescent probe for the in-situ detection of alkaline phosphatase activity.

Biochem/physiol Actions

2,3-Diaminonaphthalene (DAN) is used in the nitrite detection test, where it reacts with nitrite to form fluorescent 1H-naphthotriazol.
DAN also reacts with selenite to form 4,5-benzopiazselenol which is detectable via absorptiometry or fluorometry.

Safety Information

• pictograms: GHS08,GHS07
• signalword: Danger
• hcodes: H302,H315,H319,H335,H350
• pcodes: P201 - P202 - P301 + P312 - P302 + P352 - P305 + P351 + P338 - P308 + P313
• Hazard Classifications: Acute Tox. 4 Oral - Carc. 1A - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• target_organs: Respiratory system
• Storage Class: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• wgk: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable