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112682

Ethyl formate

reagent grade, 97%

Synonym(s):

Formic acid ethyl ester

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About This Item

Linear Formula:
HCOOC2H5
CAS Number:
Molecular Weight:
74.08
NACRES:
NA.21
PubChem Substance ID:
eCl@ss:
39022251
UNSPSC Code:
12352100
EC Number:
203-721-0
MDL number:
Beilstein/REAXYS Number:
906769
Assay:
97%
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Product Name

Ethyl formate, reagent grade, 97%

grade

reagent grade

Quality Level

vapor density

2.5 (vs air)

vapor pressure

15.16 psi ( 55 °C), 3.79 psi ( 20 °C)

assay

97%

autoignition temp.

851 °F

expl. lim.

16 %

refractive index

n20/D 1.359 (lit.)

bp

52-54 °C (lit.)

mp

−80 °C (lit.)

density

0.921 g/mL at 20 °C (lit.)

SMILES string

CCOC=O

InChI

1S/C3H6O2/c1-2-5-3-4/h3H,2H2,1H3

InChI key

WBJINCZRORDGAQ-UHFFFAOYSA-N

General description

Ethyl formate is an ethyl ester of formic acid. Its microwave spectrum indicates the presence of two isomeric forms having the ethyl group cis to the carbonyl oxygen atom but having different arrangement of the methyl group about the -CH2-O bond. Kinetics of its pyrolytic decomposition to the corresponding acid and alkene has been reported.

Application

Ethyl formate has been used in the preparation of N-(2-triethoxysilylpropyl) formamide.[1] It has been used in the synthesis of N-methyl-3-phenylbicyclo[2.2.1]heptan-2-amine hydrochloride.[2]
It may be used in the synthesis of isoflavone.

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This Item
W243434W2434181265606
assay

97%

assay

≥95%

assay

≥97%

assay

-

Quality Level

200

Quality Level

300, 400

Quality Level

300, 400

Quality Level

-

density

0.921 g/mL at 20 °C (lit.)

density

0.921 g/mL at 20 °C (lit.)

density

0.921 g/mL at 20 °C (lit.)

density

0.921 g/mL at 20 °C (lit.)

bp

52-54 °C (lit.)

bp

52-54 °C (lit.)

bp

52-54 °C (lit.)

bp

52-54 °C (lit.)

mp

−80 °C (lit.)

mp

−80 °C (lit.)

mp

−80 °C (lit.)

mp

−80 °C (lit.)

refractive index

n20/D 1.359 (lit.)

refractive index

n20/D 1.359 (lit.)

refractive index

n20/D 1.359 (lit.)

refractive index

n20/D 1.359 (lit.)


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pictograms

FlameExclamation mark

signalword

Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

3 - Flammable liquids

wgk

WGK 1

flash_point_f

-4.0 °F - closed cup

flash_point_c

-20 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves



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Eagleson M.
Concise Encyclopedia Chemistry, 413-413 (1994)
Microwave spectrum and rotational isomerism of ethyl formate.
Riveros JM and Wilson Jr EB.
J. Chem. Phys. , 46(12), 4605-4612 (1967)
Tristan F Kinde et al.
Analytical chemistry, 87(5), 2702-2709 (2015-02-11)
While the use of sodium dodecyl sulfate (SDS) in separation buffers allows efficient analysis of complex mixtures, its presence in the sample matrix is known to severely interfere with the mass-spectrometric characterization of analyte molecules. In this article, we report



Global Trade Item Number

SKUGTIN
112682-2.5L04061838700148
112682-25ML04061838700155
112682-500ML04061838700162

Questions

1–3 of 3 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

  3. Hi, Is this food grade Ethyl Formate?

    1 answer
    1. No, this product is intended for research use only. Please see the links below to review the available Flavors and Fragrances grade product options:
      https://www.sigmaaldrich.com/product/aldrich/w243418
      https://www.sigmaaldrich.com/product/aldrich/w243434

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