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For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf
1.03792
Ammonium iron(II) sulfate hexahydrate
for analysis EMSURE® ISO
Synonym(s):
Ammonium iron(II) sulfate hexahydrate
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| Pack Size | SKU | Availability | Price |
|---|
About This Item
agency
reag. ISO
Quality Level
product line
EMSURE®
assay
99.0-101.5% (manganometric)
form
solid
potency
3250 mg/kg LD50, oral (Rat)
pH
3.0-5.0 (25 °C, 5% in water)
mp
39-41 °C (decomposition)
solubility
269 g/L
density
1.86 g/cm3 at 20 °C
bulk density
900 kg/m3
anion traces
chloride (Cl-): ≤0.001%, phosphate (PO43-): ≤0.002%
cation traces
Ca: ≤0.002%, Cu: ≤0.002%, Fe3+: ≤0.02%, K: ≤0.01%, Mg: ≤0.01%, Mn: ≤0.05%, Na: ≤0.01%, Pb: ≤0.001%, Zn: ≤0.003%
storage temp.
15-25°C
SMILES string
[Fe+3].[S](=O)(=O)([O-])[O-].[S](=O)(=O)([O-])[O-].[N+H4].[N+H4].O.O.O.O.O.O
InChI
1S/Fe.2H3N.2H2O4S.6H2O/c;;;2*1-5(2,3)4;;;;;;/h;2*1H3;2*(H2,1,2,3,4);6*1H2/q+3;;;;;;;;;;/p-2
InChI key
SHHFGSWBFZVUNE-UHFFFAOYSA-L
Application
- Water-Mediated Green and Efficient Synthesis of Bis(Indolyl)methanes Using Ammonium Iron(II) Sulfate.: This research highlights the use of ammonium iron(II) sulfate hexahydrate in the green synthesis of bis(indolyl)methanes. The study demonstrates the compound′s efficiency and eco-friendliness in catalyzing reactions in water, offering a sustainable alternative in organic synthesis (Letters in Organic Chemistry, 2020).
- Determination of Ferromanganese and Ferrosilicon by Ammonium Ferrous Sulfate Titration and ICP.: This paper discusses the analytical methods for determining ferromanganese and ferrosilicon using ammonium iron(II) sulfate titration and inductively coupled plasma (ICP). The study underscores the compound′s role in precise quantitative analysis in metallurgical processes (Modern Analytical Chemistry Research, 2020).
Analysis Note
pH-value (5%; water; 25°C) 3.0 - 5.0
Chloride (Cl): ≤ 0.001 %
Phosphate (PO₄): ≤ 0.002 %
Iron(III)-salts (Fe³⁺): ≤ 0.02 %
Ca (Calcium): ≤ 0.002 %
Cu (Copper): ≤ 0.002 %
K (Potassium): ≤ 0.01 %
Mg (Magnesium): ≤ 0.01 %
Mn (Manganese): ≤ 0.05 %
Na (Sodium): ≤ 0.01 %
Pb (Lead): ≤ 0.001 %
Zn (Zinc): ≤ 0.003 %
Corresponds to ISO
Legal Information
1 of 1
This Item | |||
|---|---|---|---|
| form solid | form crystalline | form powder or crystals | form - |
| assay 99.0-101.5% (manganometric) | assay 99.997% trace metals basis | assay ≥98% | assay ≥99.0% (RT) |
| solubility 269 g/L | solubility - | solubility - | solubility H2O: 0.5 M at 20 °C, clear, faintly yellow-green |
| Quality Level 300 | Quality Level 200 | Quality Level 200 | Quality Level 100 |
| anion traces chloride (Cl-): ≤0.001%, phosphate (PO43-): ≤0.002% | anion traces - | anion traces - | anion traces chloride (Cl-): ≤10 mg/kg, phosphate (PO43-): ≤20 mg/kg |
| cation traces Cu: ≤0.002%, K: ≤0.01%, Mn: ≤0.05%, Pb: ≤0.001%, Ca: ≤0.002%, Mg: ≤0.01%, Zn: ≤0.003%, Fe3+: ≤0.02%, Na: ≤0.01% | cation traces - | cation traces - | cation traces Cd: ≤5 mg/kg, Co: ≤50 mg/kg, Cr: ≤50 mg/kg, Cu: ≤5 mg/kg, Fe3+: ≤50 mg/kg, K: ≤50 mg/kg, Mg: ≤100 mg/kg, Mn: ≤500 mg/kg, Na: ≤50 mg/kg, Ni: ≤100 mg/kg, Pb: ≤5 mg/kg, Sr: ≤5 mg/kg, Zn: ≤5 mg/kg |
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Storage Class
11 - Combustible Solids
flash_point_f
Not applicable
flash_point_c
Not applicable
Certificates of Analysis (COA)
Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.
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Global Trade Item Number
| SKU | GTIN |
|---|---|
| 1037920500 | 04022536044156 |
| 1037929050 | 04022536044200 |
| 1037925000 | 04022536044194 |
| 1037921000 | 04022536044170 |
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How is shipping temperature determined? And how is it related to the product storage temperature?
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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