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327182

tert-Butyl acrylate

contains 10-20 ppm monomethyl ether hydroquinone as inhibitor, 98%

Synonym(s):

t-Butyl acrylate

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About This Item

Linear Formula:
CH2=CHCOOC(CH3)3
CAS Number:
1663-39-4
Molecular Weight:
128.17
UNSPSC Code:
12162002
NACRES:
NA.23
PubChem Substance ID:
24859647
EC Number:
216-768-7
Beilstein/REAXYS Number:
1742329
MDL number:
MFCD00008809
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Quality Segment

200

assay

98%

form

liquid

contains

10-20 ppm monomethyl ether hydroquinone as inhibitor

refractive index

n20/D 1.410 (lit.)

bp

61-63 °C/60 mmHg (lit.)

density

0.875 g/mL at 25 °C (lit.)

SMILES string

CC(C)(C)OC(=O)C=C

InChI

1S/C7H12O2/c1-5-6(8)9-7(2,3)4/h5H,1H2,2-4H3

InChI key

ISXSCDLOGDJUNJ-UHFFFAOYSA-N

General description

tert-Butyl acrylate is an organic chemical compound that can be used as a monomer for the preparation of various types of polymers with desirable characteristics. It can undergo free-radical polymerization, which is a common method used to produce polymeric materials. Additionally, tert-butyl acrylate polymers can be copolymerized with other monomers to modify their properties. The versatility of tert-butyl acrylate makes it suitable for a wide range of applications, including coatings, adhesives, sealants, elastomers, and specialty films.

Application

tert-Butyl acrylate is a monomer used to produce poly(tert-butyl acrylate) (PtBA) polymers and copolymers, and poly(acrylic acid) polyelectrolyte brushes. It undergoes radiation polymerization to form TBA-gels for radio-fluorogenic dose imaging applications. The monomer can be used to synthesize Poly(t-butyl acrylate). It may be used as a reactive diluent in a study.

tert-Butyl acrylate can also be used as:
  • A building block in the synthesis of asymmetric membranes, which are potentially useful in filtration, separation, or gas permeation processes.
  • A monomer in the preparation of a siloxane-incorporated copolymer binder for silicon anodes in lithium-ion batteries.
  • A monomer in the synthesis of poly(tert-butyl acrylate)/carbon nanofiber (CNF) materials through atom transfer radical polymerization (ATRP).

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This Item
463353409693588458
tert-Butyl acrylate contains 10-20 ppm monomethyl ether hydroquinone as inhibitor, 98%

Sigma-Aldrich

327182

tert-Butyl acrylate

tert-Butyl methacrylate 98%, contains 200 ppm monomethyl ether hydroquinone as inhibitor

Sigma-Aldrich

463353

tert-Butyl methacrylate

Octadecyl acrylate contains 200 ppm monomethyl ether hydroquinone as inhibitor, 97%

Sigma-Aldrich

409693

Octadecyl acrylate

tert-Butyl 2-bromoacrylate 95%

Sigma-Aldrich

588458

tert-Butyl 2-bromoacrylate

assay

98%

assay

98%

assay

97%

assay

95%

density

0.875 g/mL at 25 °C (lit.)

density

0.875 g/mL at 25 °C (lit.)

density

0.8 g/mL at 25 °C (lit.)

density

1.277 g/mL at 25 °C (lit.)

form

liquid

form

-

form

solid

form

-

contains

10-20 ppm monomethyl ether hydroquinone as inhibitor

contains

200 ppm monomethyl ether hydroquinone as inhibitor

contains

200 ppm monomethyl ether hydroquinone as inhibitor

contains

-

bp

61-63 °C/60 mmHg (lit.)

bp

132 °C (lit.)

bp

-

bp

80-85 °C/35 mmHg (lit.)

refractive index

n20/D 1.410 (lit.)

refractive index

n20/D 1.415 (lit.)

refractive index

-

refractive index

n20/D 1.458 (lit.)

signalword

Danger

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Aquatic Chronic 2 - Flam. Liq. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

target_organs

Respiratory system

Storage Class

3 - Flammable liquids

wgk

WGK 2

flash_point_f

62.6 °F - closed cup

flash_point_c

17 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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Certificates of Analysis (COA)

Lot/Batch Number
MKCZ0705
MKCV4024
MKCR2148
MKCN0605
MKCL5121

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Polymer-gel formation and reformation on irradiation of tertiary-butyl acrylate
Yao T, et al.
Radiation Physics and Chemistry, 97, 147-152 (2014)
Study of the kinetics of step and flash imprint lithography photopolymerization.
Dickey MD, et al.
AIChE Journal, 51(9), 2547-2555 (2005)
Huanhuan Liu et al.
Polymers, 11(5) (2019-05-10)
Gambogenic acid (GNA) has been demonstrated with outstanding antitumor activity as a potential antitumor drug in recent years. However, the low solubility and deficient bioavailability of GNA seriously hinder its practical application in the clinic area. In this study, a
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Global Trade Item Number

SKUGTIN
327182-5ML04061826716670
327182-1L04061826716663
327182-100ML04061826716656

Questions

1–3 of 3 Questions  

  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

  3. Does this contain volatile organic compounds? Thanks.

    1 answer

    1. Volatile Organic Compound (VOC) content is not measured for item 327182.

      Helpful?

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