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16005

Paraformaldehyde

meets analytical specification of DAC, 95.0-100.5%

Synonym(s):

Polyoxymethylene

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About This Item

Linear Formula:
HO(CH2O)nH
CAS Number:
Molecular Weight:
30.03 (as monomer)
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
MDL number:
Assay:
95.0-100.5%
Technique(s):
NMR: suitable
Vapor pressure:
<1.45 mmHg ( 25 °C)
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vapor density

1.03 (vs air)

Quality Segment

vapor pressure

<1.45 mmHg ( 25 °C)

assay

95.0-100.5%

form

powder

autoignition temp.

572 °F

quality

meets analytical specification of DAC

expl. lim.

73 %

technique(s)

NMR: suitable

impurities

residual solvents, in accordance, <0.1% sulfated ash, 10 ppm heavy metals (as Pb)

mp

120-170 °C (lit.)

solubility

water: insoluble

density

0.88 g/mL at 25 °C (lit.)

suitability

in accordance for appearance of solution, suitable for acidity or alkalinity (complying)

storage temp.

2-8°C

SMILES string

[O-]#[C+H2]

InChI

1S/CH2O/c1-2/h1H2

InChI key

WSFSSNUMVMOOMR-UHFFFAOYSA-N

General description

Buffered picric acid-paraformaldehyde fixative is suitable for use in electron microscopy and light-microscopic immunocytochemistry.[1]

Application

Paraformaldehyde was used in the preparation of azomethine ylide, required for the synthesis of amine-modifying single-walled carbon nanotubes.[2] It was also used in the preparation of α-methylenechromanes, α-methylenequinoline and ortho-quinone methides.[3]

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This Item
P6148441244158127
assay

95.0-100.5%

assay

-

assay

95%

assay

95%

technique(s)

NMR: suitable

technique(s)

-

technique(s)

-

technique(s)

-

Quality Level

200

Quality Level

200

Quality Level

200

Quality Level

200

solubility

water: insoluble

solubility

-

solubility

alcohol and cold water: slightly soluble, ethers, hydrocarbons and carbon tetrachloride: insoluble

solubility

-

form

powder

form

crystalline

form

prilled

form

powder

vapor pressure

<1.45 mmHg ( 25 °C)

vapor pressure

<1.45 mmHg ( 25 °C)

vapor pressure

<1.45 mmHg ( 25 °C)

vapor pressure

<1.45 mmHg ( 25 °C)


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Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Carc. 1B - Eye Dam. 1 - Flam. Sol. 2 - Muta. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

target_organs

Respiratory system

Storage Class

4.1B - Flammable solid hazardous materials

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges



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P Somogyi et al.
Neuroscience, 7(7), 1779-1783 (1982-07-01)
The buffered picric acid paraformaldehyde fixative originally recommended for electronmicroscopy and which has since been used occasionally for light-microscopic immunocytochemistry, has been supplemented with glutaraldehyde and used as primary fixative for the perfusion of rat brains. In the basal ganglia
J Justin Mulvey et al.
International journal of nanomedicine, 9, 4245-4255 (2014-09-18)
We aimed to create a more robust and more accessible standard for amine-modifying single-walled carbon nanotubes (SWCNTs). A 1,3-cycloaddition was developed using an azomethine ylide, generated by reacting paraformaldehyde and a side-chain-Boc (tert-Butyloxycarbonyl)-protected, lysine-derived alpha-amino acid, H-Lys(Boc)-OH, with purified SWCNT
José C J M D S Menezes et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 20(42), 13644-13655 (2014-08-30)
In view of increasing demands for efficient photosensitizers for photodynamic therapy (PDT), we herein report the synthesis and photophysical characterizations of new chlorin e6 trimethyl ester and protoporphyrin IX dimethyl ester dyads as free bases and Zn(II) complexes. The synthesis of these



Global Trade Item Number

SKUGTIN
16005-1KG-R04061838744951
16005-250G-F04061838744968
16005-6X1KG-R04061832489308
16005-25KG-R04061832489292
16005-1KG-F04061838744944

Questions

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  3. What is the Department of Transportation shipping information for this product?

    1 answer
    1. Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product.

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