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116017

2-Carboxybenzaldehyde

97%

Synonym(s):

Phthalaldehydic acid, 2-Formylbenzoic acid, 3-Hydroxyphthalide

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About This Item

Empirical Formula (Hill Notation):
C8H6O3
CAS Number:
Molecular Weight:
150.13
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
204-342-3
Beilstein/REAXYS Number:
742381
MDL number:
Assay:
97%
Form:
solid
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Quality Segment

assay

97%

form

solid

mp

94-96 °C (lit.)

functional group

aldehyde, carboxylic acid

SMILES string

OC(=O)c1ccccc1C=O

InChI

1S/C8H6O3/c9-5-6-3-1-2-4-7(6)8(10)11/h1-5H,(H,10,11)

InChI key

DYNFCHNNOHNJFG-UHFFFAOYSA-N

General description

2-Carboxybenzaldehyde is an aldehydic acid that can be used to synthesize functionalized diazaphospholanes.

Application

2-Carboxybenzaldehyde is a metabolite of the biodegradation of luoranthene using two pure bacterial strains, Pasteurella sp. IFA (B-2) and Mycobacterium sp. PYR-1 (AM)[1]. It has been used to synthesize a series of N-substituted isoindolinones by reductive C-N coupling and intramolecular amidation with amines[2].

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This Item
667994K401739138
assay

97%

assay

97%

assay

97%

assay

97%

Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

100

form

solid

form

solid

form

liquid

form

solid

mp

94-96 °C (lit.)

mp

134-138 °C

mp

30-34 °C (lit.)

mp

87-92 °C

functional group

aldehyde, carboxylic acid

functional group

carboxylic acid

functional group

-

functional group

carboxylic acid, iodo


pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves



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E Sepic et al.
Journal of applied microbiology, 85(4), 746-754 (1998-11-13)
The findings from a biodegradability study of fluoranthene using two pure bacterial strains, Pasteurella sp. IFA (B-2) and Mycobacterium sp. PYR-1 (AM) are reported. Of total fluoranthene, 24% (B-2) and 46% (AM) was biodegraded in an aqueous medium during 14
Solid-phase synthesis of chiral 3, 4-diazaphospholanes and their application to catalytic asymmetric allylic alkylation
Landis CR and Clark TP
Proceedings of the National Academy of Sciences, 101, 5428-5432 (2004)
Linyan Shi et al.
Organic letters, 14(7), 1876-1879 (2012-03-17)
A series of N-substituted isoindolinones have been successfully synthesized through the reductive C-N coupling and intramolecular amidation of 2-carboxybenzaldehyde and amines. This one-pot synthesis gives excellent yields using ultrathin Pt nanowires as catalysts under 1 bar of hydrogen. These unsupported



Global Trade Item Number

SKUGTIN
116017-25G04061838704016
116017-100G04061838704009

Questions

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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