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26420

Chloro(2,2′:6′,2″-terpyridine)platinum(II) chloride dihydrate

≥99.0% (AAS)

Synonym(s):

Dichloro(2,2′:6′,2′′-terpyridine)platinum(II) dihydrate

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About This Item

Empirical Formula (Hill Notation):
C15H11Cl2N3Pt · 2H2O
CAS Number:
151120-25-1
Molecular Weight:
535.28
NACRES:
NA.32
PubChem Substance ID:
57648171
UNSPSC Code:
12171500
MDL number:
MFCD00149950
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assay

≥99.0% (AAS)

SMILES string

O.O.Cl[Pt]Cl.c1ccc(nc1)-c2cccc(n2)-c3ccccn3

InChI

1S/C15H11N3.2ClH.2H2O.Pt/c1-3-10-16-12(6-1)14-8-5-9-15(18-14)13-7-2-4-11-17-13;;;;;/h1-11H;2*1H;2*1H2;/q;;;;;+2/p-2

InChI key

WEBUYGBVKZYTMT-UHFFFAOYSA-L

Other Notes

An intercalator of helical and double stranded DNA; Spectroscopic tag for proteins. Selective covalent labeling of histidine in cytochromes c; Intercalation[1]

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This Item
401609SML255696738
Chloro(2,2′:6′,2″-terpyridine)platinum(II) chloride dihydrate ≥99.0% (AAS)

Sigma-Aldrich

26420

Chloro(2,2′:6′,2″-terpyridine)platinum(II) chloride dihydrate

(2,2′-Bipyridine)dichloroplatinum(II) 96%

Sigma-Aldrich

401609

(2,2′-Bipyridine)dichloroplatinum(II)

Pt-ttpy >97% (NMR)

Sigma-Aldrich

SML2556

Pt-ttpy

(R)-(+)-5,5′-Dichloro-2,2′-bis(diphenylphosphino)-6,6′-dimethoxy-1,1′-biphenyl ≥95.0% (H-NMR)

Sigma-Aldrich

96738

(R)-(+)-5,5′-Dichloro-2,2′-bis(diphenylphosphino)-6,6′-dimethoxy-1,1′-biphenyl

assay

≥99.0% (AAS)

assay

96%

assay

>97% (NMR)

assay

≥95.0% (H-NMR)

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
285634/1

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K W Jennette et al.
Proceedings of the National Academy of Sciences of the United States of America, 71(10), 3839-3843 (1974-10-01)
The red, cationic complex 2-hydroxy-ethanethiolato(2,2',2''-terpyridine)platinum(II), [(terpy)-Pt(SCH(2)CH(2)OH)](+), binds strongly to DNA by a mechanism involving intercalation. By means of fluorescence spectroscopy, the platinum complex was shown to inhibit competitively the binding of the intercalating dye ethidium bromide to calf thymus DNA.
E.M.A. Ratilla et al.
Journal of the American Chemical Society, 109, 4592-4592 (1987)
S. J. Lippard
Accounts of Chemical Research, 11, 211-211 (1987)

Global Trade Item Number

SKUGTIN
26420-25MG04061833276952

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