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Dichloro(1,5-cyclooctadiene)ruthenium(II), polymer

Name: Dichloro(1,5-cyclooctadiene)ruthenium(II), polymer
Brand: ALDRICH

95%

Synonym(s):

(1,5-Cyclooctadiene)ruthenium(II) chloride, Ruthenium(II) chloride 1,5-cyclooctadiene complex

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About This Item

Linear Formula:

[Ru(COD)Cl₂]_n

CAS Number:

50982-12-2

Molecular Weight:

280.16 (as monomer)

MDL number:

MFCD00171304

UNSPSC Code:

12161600

NACRES:

NA.22

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Properties

Quality Segment

200

assay

95%

reaction suitability

core: ruthenium, reaction type: solution phase peptide synthesis, reagent type: catalyst

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

greener alternative category

, Aligned

SMILES string

[Ru+2].[Cl-].[Cl-].C1CC=CCCC=C1

InChI

1S/C8H12.2ClH.Ru/c1-2-4-6-8-7-5-3-1;;;/h1-2,7-8H,3-6H2;2*1H;/q;;;+2/p-2

InChI key

DMRVBCXRFYZCPR-UHFFFAOYSA-L

Description

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Application

Versatile Ru catalyst precursor. Used with IMes to catalyze the dehydrogenative coupling of alcohols and amines to form amide bonds.

Versatile ruthenium catalyst precursor. Used with NHC ligand to catalyze greener amide bond formation by dehydrogenative coupling of amines and alcohols.

Amide Synthesis from Alcohols and Amines by the Extrusion of Dihydrogen

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This Item	343706	746339	227951
Sigma-Aldrich 337331 Dichloro(1,5-cyclooctadiene)ruthenium(II), polymer	Sigma-Aldrich 343706 Dichloro(p-cymene)ruthenium(II) dimer	Sigma-Aldrich 746339 Dichlorotriphenylphosphine[bis(2-(ethylthio)ethyl)amine]ruthenium(II)	Sigma-Aldrich 227951 Chloro(1,5-cyclooctadiene)rhodium(I) dimer
reaction suitability core: ruthenium, reagent type: catalyst, reaction type: solution phase peptide synthesis	reaction suitability core: ruthenium, reagent type: catalyst reaction type: C-H Activation	reaction suitability -	reaction suitability core: rhodium, reagent type: catalyst
assay 95%	assay ≥95%	assay 97%	assay 98%
Quality Level 200	Quality Level 100	Quality Level 100	Quality Level 100
sustainability Greener Alternative Product	sustainability Greener Alternative Product	sustainability Greener Alternative Product	sustainability Greener Alternative Product
greener alternative product characteristics Catalysis Learn more about the Principles of Green Chemistry.	greener alternative product characteristics Catalysis Learn more about the Principles of Green Chemistry.	greener alternative product characteristics Catalysis Learn more about the Principles of Green Chemistry.	greener alternative product characteristics Catalysis Learn more about the Principles of Green Chemistry.
greener alternative category , Aligned	greener alternative category , Aligned	greener alternative category Aligned,	greener alternative category Aligned,

pictograms

GHS07

signalword

Warning

hcodes

H315,H319

pcodes

P264 - P280 - P302 + P352 - P305 + P351 + P338 - P332 + P313 - P337 + P313

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2

Storage Class

11 - Combustible Solids

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves

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