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For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf
Przejdź do
335363
[1,3-Bis(diphenylphosphino)propane]dichloronickel(II)
powder
Synonim(y):
(1,3-dppp)NiCl2, 1,3-Bis(diphenylphosphino)propane nickel(II) chloride, Ni(dppp)Cl2
Wybierz wielkość
| Rozmiar/SKU | Dostępność | Cena netto |
|---|---|---|
5 g | Skontaktuj się z Obsługą Klienta, aby uzyskać informacje na temat dostępności | 365,00 zł |
25 g | Skontaktuj się z Obsługą Klienta, aby uzyskać informacje na temat dostępności | 674,00 zł |
Informacje o tej pozycji
365,00 zł
Nazwa produktu
[1,3-Bis(diphenylphosphino)propane]dichloronickel(II),
form
powder
Quality Segment
reaction suitability
core: nickel, reaction type: Cross Couplings, reagent type: catalyst
mp
213 °C (dec.) (lit.)
SMILES string
Cl[Ni]Cl.C(CP(c1ccccc1)c2ccccc2)CP(c3ccccc3)c4ccccc4
InChI
1S/C27H26P2.2ClH.Ni/c1-5-14-24(15-6-1)28(25-16-7-2-8-17-25)22-13-23-29(26-18-9-3-10-19-26)27-20-11-4-12-21-27;;;/h1-12,14-21H,13,22-23H2;2*1H;/q;;;+2/p-2
InChI key
ZBQUMMFUJLOTQC-UHFFFAOYSA-L
Application
- Synthesis of block-copolythiophenes
- Suzuki-Miyaura cross-coupling reaction of aryl halides with arylboronic acids
- Solid state metathesis polycondensation
- Polymerization of poly(3-alkoxythiophene)s
- Diastereoselective Nozaki-Hiyama-Kishi coupling reactions of C1-C19 fragment of macrolide antibiotic aplyronine A
- Transfer condensation polymerization of conjugated polymers
1 of 1
Ta pozycja | |||
|---|---|---|---|
| description - | description - | description ≥95% | description 97% |
| reaction suitability reaction type: Cross Couplings, reagent type: catalyst, core: nickel | reaction suitability core: nickel, reagent type: catalyst | reaction suitability reagent type: catalyst | reaction suitability reagent type: ligand |
| form powder | form solid | form powder | form solid |
| Quality Level 100 | Quality Level 100 | Quality Level - | Quality Level 200 |
| mp 213 °C (dec.) (lit.) | mp 263-265 °C (lit.) | mp 322-326 °C | mp 63-65 °C (lit.) |
Słowo ostrzegawcze
Danger
Kody zagrożeń
Hazard Classifications
Carc. 1A - Eye Irrit. 2 - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3
Narządy docelowe
Respiratory system
Klasa składowania
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
Co się dzieje?
WGK 3
Temperatura zapłonu (°F)
Not applicable
Temperatura zapłonu (°C)
Not applicable
PPE (środki ochrony indywidualnej)
Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
Wykazy regulacyjne
Wykazy regulacyjne dotyczą głównie produktów chemicznych. Można w nich podawać ograniczoną liczbę informacji na temat produktów niechemicznych. Brak wpisu oznacza, że żaden ze składników nie znajduje się w wykazie. Użytkownik odpowiada za zagwarantowanie bezpiecznego i zgodnego z prawem stosowania produktu.
15629-92-2
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How can I determine the shelf life / expiration / retest date of this product?
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How is shipping temperature determined? And how is it related to the product storage temperature?
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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