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1.05033

Potassium hydroxide

pellets for analysis EMSURE®

Synonym(s):

Potash caustic, Caustic potash

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About This Item

Linear Formula:
KOH
CAS Number:
Molecular Weight:
56.11
NACRES:
NA.21
EC Index Number:
215-181-3
UNSPSC Code:
12352305
MDL number:
eCl@ss:
38100303
Assay:
≥85.0% KOH basis (acidimetric)
Grade:
reagent grade
Form:
solid
Solubility:
1130 g/L
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Quality Segment

grade

reagent grade

agency

suitable for SM 5210

vapor pressure

1 mmHg ( 719 °C)

product line

EMSURE®

assay

≥85.0% KOH basis (acidimetric)

form

solid

potency

333 mg/kg LD50, oral (Rat)

pH

14 (20 °C, 56 g/L in H2O)

mp

361 °C (lit.)

solubility

1130 g/L

anion traces

carbonate (K2CO3): ≤1.0%, chloride (Cl-): ≤0.005%, phosphate (PO43-): ≤0.0005%, silicate (as SiO2): ≤0.005%, sulfate (SO42-): ≤0.0005%

cation traces

Al: ≤0.001%, Ca: ≤0.001%, Cu: ≤0.0002%, Fe: ≤0.0005%, N: ≤0.0005%, Na: ≤0.5%, Ni: ≤0.0005%, Pb: ≤0.0005%, Zn: ≤0.0025%, heavy metals (as Pb): ≤0.0005%

storage temp.

2-30°C

SMILES string

[OH-].[K+]

InChI

1S/K.H2O/h;1H2/q+1;/p-1

InChI key

KWYUFKZDYYNOTN-UHFFFAOYSA-M

Application

Potassium hydroxide (KOH) can be used:
  • To precipitate perchlorate ions after the addition of perchloric acid during the extraction of intracellular metabolites from yeast. It is also utilized to adjust the pH of the solution, ensuring optimal conditions for subsequent analysis.
  • In corrosion testing of anodized aluminium alloys to evaluate mass loss and corrosion resistance of the anodic layer.
  • To basify reaction mixtures, facilitating the derivatization needed for gas chromatography-mass spectrometry (GC-MS) analysis in the identification of metabolic precursors.

Analysis Note

Assay (acidimetric, KOH): ≥ 85.0 %
Carbonate (as K₂CO₃): ≤ 1.0 %
Chloride (Cl): ≤ 0.005 %
Phosphate (PO₄): ≤ 0.0005 %
Silicate (SiO₂): ≤ 0.005 %
Sulfate (SO₄): ≤ 0.0005 %
Total nitrogen (N): ≤ 0.0005 %
Heavy metals (as Pb): ≤ 0.0005 %
Al (Aluminium): ≤ 0.001 %
Ca (Calcium): ≤ 0.001 %
Cu (Copper): ≤ 0.0002 %
Fe (Iron): ≤ 0.0005 %
Na (Sodium): ≤ 0.5 %
Ni (Nickel): ≤ 0.0005 %
Pb (Lead): ≤ 0.0005 %
Zn (Zinc): ≤ 0.0025 %

Legal Information

EMSURE is a registered trademark of Merck KGaA, Darmstadt, Germany

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1 of 1

This Item
1.050121.0503260370
form

solid

form

solid

form

solid

form

pellets

solubility

1130 g/L

solubility

water: complete

solubility

-

solubility

alcohol: soluble(lit.), water: soluble(lit.)

assay

≥85.0% KOH basis (acidimetric)

assay

≥84.0% KOH basis (acidimetric)

assay

-

assay

≥86% (T)

Quality Level

300

Quality Level

200

Quality Level

500

Quality Level

100

grade

reagent grade

grade

reagent grade

grade

-

grade

-

vapor pressure

1 mmHg ( 719 °C)

vapor pressure

1 mmHg ( 719 °C)

vapor pressure

1 mmHg ( 719 °C)

vapor pressure

1 mmHg ( 719 °C)


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pictograms

CorrosionExclamation mark

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1A

Storage Class

8B - Non-combustible corrosive hazardous materials

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable



Certificates of Analysis (COA)

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Global Trade Item Number

SKUGTIN
105033500004022536059631
105033100004022536059617
105033902504022536531878
105033905004022536059655
105033050004022536059594

Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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