The chemicals encyclopedia published by the Royal Society of Chemistry (13th ed.) indicates that this product is expected to be miscible in hydrocarbons, including benzene, ether, and petroleum ether.
製品256781は現在お客様の国では販売されていません。 製品に関するお問い合わせはこちら（テクニカルサービス）
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品質水準
フォーム
liquid
濃度
≥52 wt. % Zn
屈折率
n20/D 1.498 (lit.)
bp
117 °C (lit.)
mp
−28 °C (lit.)
密度
1.205 g/mL at 25 °C (lit.)
SMILES記法
CC[Zn]CC
InChI
1S/2C2H5.Zn/c2*1-2;/h2*1H2,2H3;
InChI Key
HQWPLXHWEZZGKY-UHFFFAOYSA-N
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アプリケーション
包装
Supplied in a Sure/Pac™ cylinder and has a 1/4-turn bronze ball valve with a female 1/4" NPT outlet thread (Z122661) installed. Before using the cylinder, ensure that the valve is closed, then remove carbon steel plug that seals the outlet valve.
Compatible with the following:
Compatible with the following:
- Aldrich® Sure/Pac™ station for liquefied gases Z566446
- PTFE Sealing tape Z104388 or Z221880
- Straight septum-inlet adapter Z118141 with septa Z565687 or Z565695
法的情報
Aldrich is a registered trademark of Sigma-Aldrich Co. LLC
Sure/Pac is a trademark of Sigma-Aldrich Co. LLC
よく一緒に購入される製品
セプタム インレット アダプター
シグナルワード
Danger
危険有害性情報
危険有害性の分類
Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Pyr. Liq. 1 - Skin Corr. 1B - Water-react 1
補足的ハザード
保管分類コード
4.2 - Pyrophoric and self-heating hazardous materials
WGK
WGK 3
個人用保護具 (PPE)
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
適用法令
試験研究用途を考慮した関連法令を主に挙げております。化学物質以外については、一部の情報のみ提供しています。 製品を安全かつ合法的に使用することは、使用者の義務です。最新情報により修正される場合があります。WEBの反映には時間を要することがあるため、適宜SDSをご参照ください。
消防法
第3類:自然発火性物質及び禁水性物質
有機金属化合物(アルキルアルミニウム及びアルキルリチウムを除く)を含有するもの
危険等級I
第一種自然発火性物質及び禁水性物質
Jan Code
256781-BULK:
256781-VAR:
256781-100G:
Bifunctional catalysts based on colloidal Cu/Zn nanoparticles for the direct conversion of synthesis gas to dimethyl ether and hydrocarbons
Gentzen, M and Doronkin, DE and Sheppard, TL and Grunwaldt, J-D and Sauer, J and Behrens, S
Applied Catalysis A: General, 557, 99-107 (2018)
Single-site zinc on silica catalysts for propylene hydrogenation and propane dehydrogenation: Synthesis and reactivity evaluation using an integrated atomic layer deposition-catalysis instrument
Camacho-Bunquin J, et al.
J. Catal., 345, 170-182 (2017)
Bifunctional hybrid catalysts derived from Cu/Zn-based nanoparticles for single-step dimethyl ether synthesis
Gentzen, M and Habicht, W and Doronkin, DE and Grunwaldt, J-D and Sauer, J and Behrens, S
Catalysis Science & Technology, 6(4), 1054-1063 (2016)
Tummanapalli Satyanarayana et al.
Organic letters, 9(2), 251-253 (2007-01-16)
A strong asymmetric amplification is observed in the addition of diethylzinc on aromatic aldehydes in the presence of the bistriflamide of trans-1,2-diaminocyclohexane 3a. The asymmetric amplification originates from the insolubility of the catalyst precursor 3a of low enantiomeric excess (ee)
Weimin Lin et al.
The Journal of organic chemistry, 74(2), 645-651 (2008-12-06)
The application of a zinc carbenoid-mediated chain-extension reaction to a functionalized peptide isostere is reported. The cleavage site of human CVM protease was utilized as a target for testing the synthetic methodology. The utility of this chain-extension reaction is demonstrated
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What is Product 256781, Diethylzinc, soluble in?
1 回答-
役に立ちましたか？
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What do I do with the Product 256781, Diethylzinc, bottle once it is empty?
1 回答-
Product 256781 is packed in a Sure/Pac cylinder. When the contents of the cylinder have been exhausted Sigma-Aldrich recommends that a licensed waste disposal company be contacted for the appropriate means to dispose of this container. Some residual product might remain in the container and should not be discarded with general waste. Alternatively, Sigma-Aldrich does offer an option for returning empty Sure/Pac cylinders. The customer will be required to pay for the return shipping and a minimal disposal charge, as Sigma-Aldrich does not require these cylinders to be returned. Additional information on the Sure/Pac return program can be obtained by contacting customer service at 800-325-3010.
役に立ちましたか？
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What is the Department of Transportation shipping information for this product?
1 回答-
Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product.
役に立ちましたか？
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How do I remove Product 256781, Diethylzinc, from the container?
1 回答-
This product is air sensitive and is package under inert gas. Transfer of this product should be conducted under inert atmosphere (such as in a glove box or Atmosbag) to reduce the chance of exposure of the chemical to the atmosphere. Additional details about how to handle and store air-sensitive materials can be found in Sigma-Aldrich technical bulletin AL-134.
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