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208566

Sigma-Aldrich

Titanium(IV) chloride

ReagentPlus®, 99.9% trace metals basis

Szinonimák:

TTC, Titanium tetrachloride

Bejelentkezésa Szervezeti és Szerződéses árazás megtekintéséhez

Méret kiválasztása

200 G
32 900,00 Ft
1.5 KG
154 000,00 Ft

32 900,00 Ft

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Megrendelés igénylése nagy tételben
Összes fotó(1)

Méret kiválasztása

Nézet módosítása
200 G
32 900,00 Ft
1.5 KG
154 000,00 Ft

About This Item

Lineáris képlet:
TiCl4
CAS-szám:
7550-45-0
Molekulatömeg:
189.68
EC-szám:
231-444-5
MDL-szám:
MFCD00011267
UNSPSC kód:
12352300
PubChem Substance ID:
329752044
NACRES:
NA.55
Teszt:
99.9% trace metals basis
Forma:
liquid

32 900,00 Ft

Az elérhetőséggel kapcsolatos kérdésekkel kérjük, forduljon Vevőszolgálatunkhoz.
Megrendelés igénylése nagy tételben

gőznyomás

50 mmHg ( 55 °C)
9.6 mmHg ( 20 °C)

Minőségi szint

100
200

termékcsalád

ReagentPlus®

Teszt

99.9% trace metals basis

Forma

liquid

reakcióalkalmasság

reagent type: catalyst
core: titanium

bp

135-136 °C (lit.)

mp

−25 °C (lit.)

sűrűség

1.73 g/mL at 20 °C (lit.)

SMILES string

Cl[Ti](Cl)(Cl)Cl

InChI

1S/4ClH.Ti/h4*1H;/q;;;;+4/p-4

Nemzetközi kémiai azonosító kulcs

XJDNKRIXUMDJCW-UHFFFAOYSA-J

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Általános leírás

Titanium(IV) chloride participates in the Baylis-Hillman reaction of arylaldehydes with methyl vinyl ketone.[1] Neutral solutions of TiCl4 having a pH in the range of 2.5 to 6.0 (prepared by the addition of magnesium oxide as a base) have been used for the synthesis of nanosized titanium dioxide.[2]

Alkalmazás

Activates pyrrolidines for improved conversion, via a modified Bouveault reaction, to the corresponding α,α-dimethylamines.[3]
Along with sodium borohydride, it forms an effective reagent for the reduction of:[4]
  • carboxylic acid and acyl chloride to alcohols
  • carboxamides, oximes and lactams to amines
  • sulfoxides to sulfides
Titanium(IV) chloride (TiCl4) has been used as a precursor for the synthesis of Ag-TiO2@polyethylene glycol (PEG) nanoparticles.[5] TiCl4 may also be used as one of the constituents to synthesize TiO2/Al2O3 binary oxide materials[6] and N-(10-oxo-vinylanthracen-9-(10H)-ylidene)cyanamide.[7]

Jogi információk

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

Piktogramok

Skull and crossbonesCorrosion
GHS06,GHS05

Figyelmeztetés

Danger

Figyelmeztető mondatok

H314,H330,H335

Veszélyességi osztályok

Acute Tox. 1 Inhalation - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3

Célzott szervek

Respiratory system

Egyéb veszélyek

EUH014

Tárolási osztály kódja

6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 1

Lobbanási pont (F)

Not applicable

Lobbanási pont (C)

Not applicable

Válasszon a legfrissebb verziók közül:

Analitikai tanúsítványok (COA)

Lot/Batch Number
SHBR8678
SHBQ9571
SHBQ9572
SHBQ6697
SHBQ1519

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Reduction of some functional groups with titanium (IV) chloride/sodium borohydride.
Kano S, et al.
Synthesis, 1980(09), 695-697 (1980)
Gaofei Xiao et al.
Journal of environmental sciences (China), 60, 14-23 (2017-10-17)
TiO
Scalable hybrid chemical manufacture to photothermal therapy: PEG-capped phototransducers
Byeon, Jeong Hoon
Scientific Reports, 6 (2016)
Poly [N-(10-oxo-2-vinylanthracen-9(10H)-ylidene) cyanamide] as a novel cathode material for li-organic batteries.
Schmidt D, et al.
Journal of Polymer Science Part A: Polymer Chemistry, 53(21), 2517-2523 (2015)
Influence of the sol-gel preparation method on the photocatalytic NO oxidation performance of TiO2/Al2O3 binary oxides.
Polat M, et al.
Catalysis Today, 241, 25-32 (2015)
View All Related Papers

Questions

1–6 of 6 Questions  

  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

  3. what is the concentration of this product TiCl4 ReagentPlus®, 99.9% trace metals basis 200 gm?

    1 answer

    1. This product is a neat or pure liquid. The material has a density of 1.73 g/mL at 20 °C and a molecular weight of 189.69. The concentration of the pure compound is 9.1M

      Helpful?

  4. how is this item packaged?

    1 answer

    1. The packaging for the 200g is a 100ml amber glass bottle with a Sure/Seal cap. The packaging for the 1.5kg is a 1L amber glass bottle with a Sure/Seal cap. To learn more about the Sure/Seal packaging system please see the link below:
      https://www.sigmaaldrich.com/technical-documents/technical-article/chemistry-and-synthesis/organic-reaction-toolbox/sureseal

      Helpful?

  5. What is Product 208566, Titanium(IV) chloride, soluble in?

    1 answer

    1. Per the chemicals encyclopedia published by the Royal Society of Chemistry, Titanium(IV) Chloride is soluble in cold water and alcohol.

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  6. What is the Department of Transportation shipping information for this product?

    1 answer

    1. Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product.

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