Összes fotó(1)
Fontos dokumentumok
175552
Trichlorosilane
99%
Szinonimák:
Hydrotrichlorosilane, Silicochloroform, Silicon chloride hydride, Trichloromonosilane
Bejelentkezésa Szervezeti és Szerződéses árazás megtekintéséhez
Összes fotó(1)
About This Item
Lineáris képlet:
SiHCl3
CAS-szám:
Molekulatömeg:
135.45
EC-szám:
MDL-szám:
UNSPSC kód:
12352101
PubChem Substance ID:
NACRES:
NA.22
Javasolt termékek
gőzsűrűség
1 (vs air)
Minőségi szint
gőznyomás
9.75 psi ( 20 °C)
Teszt
99%
Forma
liquid
robbanási határérték
70 %
bp
32-34 °C (lit.)
sűrűség
1.342 g/mL at 25 °C (lit.)
tárolási hőmérséklet
2-8°C
SMILES string
Cl[SiH](Cl)Cl
InChI
1S/Cl3HSi/c1-4(2)3/h4H
Nemzetközi kémiai azonosító kulcs
ZDHXKXAHOVTTAH-UHFFFAOYSA-N
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Related Categories
Általános leírás
Trichlorosilane is used as a reducing agent in certain chemical reactions or as a starting material for the synthesis of various organosilicon compounds. Trichlorosilane is generally used for the asymmetric hydrosilylation of olefins in the presence of palladium catalysts coordinated with chiral monodentate phosphorus ligands to generate chiral organosilanes.
Alkalmazás
Trichlorosilane has been used to synthesize 11-dicyclohexylphosphino-12-phenyl-9,10-dihydro-9,10-ethenoanthracene (H-KITPHOS) via reduction of 11-dicyclohexylphosphinoyl-12-phenyl-9,10-dihydro-9,10-ethenoanthracene.
Other possible applications:
L-valine-derived catalyst to form secondary amines.
derivatives is an effective reagent for the reduction of imines to form
enantiomerically enriched amines.
Other possible applications:
- Asymmetric reduction of N-aryl ketimines in the presence of a novel
L-valine-derived catalyst to form secondary amines.
- Hydrosilylation of imidazolinones to form chiral imidazolidinones in the presence of a 2,2′-bispyrrolidine based Lewis base organocatalyst.
- Trichlorosilane activated with chiral N-formylproline
derivatives is an effective reagent for the reduction of imines to form
enantiomerically enriched amines.
- Trichlorosilane reacts with dimethylformamide to form hypervalent hydridosilicates, which can reduce aldehydes to alcohols, imines to amines, and also for the reductive amination of aldehydes.
Figyelmeztetés
Danger
Figyelmeztető mondatok
Óvintézkedésre vonatkozó mondatok
Veszélyességi osztályok
Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 1 - Skin Corr. 1A - Water-react 1
Egyéb veszélyek
Tárolási osztály kódja
4.3 - Hazardous materials which set free flammable gases upon contact with water
WGK
WGK 1
Lobbanási pont (F)
<-2.2 °F - Equilibrium method
Lobbanási pont (C)
< -19 °C - Equilibrium method
Egyéni védőeszköz
Faceshields, Gloves, Goggles
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