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1.00573

ortho-Phosphoric acid

greener alternative

85%, for analysis EMSURE® ACS,ISO,Reag. Ph Eur

Synonym(s):

Phosphoric acid, o-Phosphoric acid, Orthophosphoric acid, Orthophosphoric acid

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About This Item

Linear Formula:
H3PO4
CAS Number:
Molecular Weight:
98.00
NACRES:
NA.21
UNSPSC Code:
12352301
MDL number:
Beilstein/REAXYS Number:
1921286
eCl@ss:
38070202
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Product Name

ortho-Phosphoric acid 85%, for analysis EMSURE® ACS,ISO,Reag. Ph Eur

grade

ACS reagent

Quality Level

agency

reag. ISO, reag. Ph. Eur.

vapor density

3.4 (vs air)

vapor pressure

2.2 mmHg ( 20 °C), 5 mmHg ( 25 °C)

product line

EMSURE®

form

liquid

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

concentration

85% phosphoric acid

impurities

≤0.5 ppm As (Arsenic), ≤0.5 ppm Cd (Cadmium), ≤0.5 ppm Co (Cobalt), ≤0.5 ppm Cu (Copper), ≤0.5 ppm Mn (Manganese), ≤0.5 ppm Pb (Lead), ≤1 ppm Fluoride (F), ≤1.0 ppm Ni (Nickel), ≤10 ppm Fe (Iron), ≤10 ppm Heavy metals (as Pb), ≤10 ppm Insoluble matter, ≤10 ppm Substances reducing potassium permanganate (as O), ≤10 ppm Volatile acids (as Acetic acid), ≤2 ppm Chloride (Cl), ≤2 ppm Zn (Zinc), ≤20 ppm Ca (Calcium), ≤20 ppm Phosphite and Hypophosphite (as H3PO3), ≤20 ppm Sulfate (SO4), ≤200 ppm Na (Sodium), ≤3 ppm Nitrate (NO3), ≤5 ppm K (Potassium), ≤5 ppm Mg (Magnesium), ≤5 ppm Sb (Antimony)

color

APHA: ≤10

pH

<0.5 (20 °C, 100 g/L in H2O)

kinematic viscosity

30.5 cSt(20 °C)

bp

158 °C (lit.)

mp

~40 °C (lit.)

density

1.685 g/mL at 25 °C (lit.)

greener alternative category

SMILES string

OP(O)(O)=O

storage temp.

no temp limit

InChI

1S/H3O4P/c1-5(2,3)4/h(H3,1,2,3,4)

InChI key

NBIIXXVUZAFLBC-UHFFFAOYSA-N

General description

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for analysis EMSURE® ACS,ISO,Reag. Ph Eur

Application

ortho-Phosphoric acid can be used as a:
  • Reactant in the synthesis of polyurethane ionomer films through etherification with polyoxypropylene glycol in the presence of tertiary amines.
  • Catalyst in pinacolic rearrangement reactions when it is supported on silica.
  • Phosphorus source in the synthesis of diaryl phosphates.

Analysis Note

Assay (alkalimetric)≥ 85.0 %Identitypasses testAppearance of solutionpasses testColor≤ 10 HazenChloride (Cl)≤ 2 ppmFluoride (F)≤ 1 ppmNitrate (NO₃)≤ 3 ppmPhosphite and Hypophosphite (as H₃PO₃)≤ 20 ppmHypophosphite, phosphitepasses testHeavy metals (as Pb)≤ 10 ppmSulfate (SO₄)≤ 20 ppmAs (Arsenic)≤ 0.5 ppmCa (Calcium)≤ 20 ppmCd (Cadmium)≤ 0.5 ppmCo (Cobalt)≤ 0.5 ppmCu (Copper)≤ 0.5 ppmFe (Iron)≤ 10 ppmK (Potassium)≤ 5 ppmMg (Magnesium)≤ 5 ppmMn (Manganese)≤ 0.5 ppmNa (Sodium)≤ 200 ppmNi (Nickel)≤ 1.0 ppmPb (Lead)≤ 0.5 ppmSb (Antimony)≤ 5 ppmZn (Zinc)≤ 2 ppmMatter precipitated by ammoniapasses testVolatile acids (as Acetic acid)≤ 10 ppmSubstances reducing potassium permanganate (as O)≤ 10 ppmInsoluble matter≤ 10 ppm

Other Notes

Concentrated phosphoric acid is approx. 85% H3PO4 (aqueous).

Legal Information

EMSURE is a registered trademark of Merck KGaA, Darmstadt, Germany

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grade

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concentration

85% phosphoric acid

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product line

EMSURE®

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form

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density

1.685 g/mL at 25 °C (lit.)

density

1.685 g/mL at 25 °C (lit.)

density

1.685 g/mL at 25 °C (lit.)

density

1.053 g/cm3 at 20 °C


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pictograms

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signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B

flash_point_f

does not flash

flash_point_c

does not flash

Storage Class

8B - Non-combustible corrosive hazardous materials



Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Global Trade Item Number

SKUGTIN
100573100004022536008141
100573051004054839164132
100573902504022536008189
100573251004027269218171
100573902804027269301958
100573250004022536008165
100573920004027269685652
100573250804027269301941

Questions

1–3 of 3 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

  3. acido fosforico 85% (solo per TOC-L CS H) quale scelgo?

    1 answer
    1. This product is supplied in several different pack sizes that are packaged in either glass or plastic.

      For more assistance on which may be the best for your application, we kindly ask you to navigate to the link https://www.sigmaaldrich.com/techservice, click on "Product Technical Inquires" under the Products Section with all the required information so that a member of our team can reach out to you to assist further. Thank you.

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