C1017

Citrinin

from Penicillium citrinum, ≥98% (HPLC), powder, mycotoxin

• Synonym(s): (3R,4S)-8-Hydroxy-3,4,5-Trimethyl-6-Oxo-4,6-Dihydro-3H-Isochromene-7-Carboxylic Acid, 4,6-Dihydro-8-hydroxy-3,4,5-trimethyl-6-oxo-3H-2-benzopyran-7-carboxylic acid
• Empirical Formula (Hill Notation): C₁₃H₁₄O₅
• CAS Number: 518-75-2
• Molecular Weight: 250.25
• NACRES: NA.77
• PubChem Substance ID: 24892302
• UNSPSC Code: 12352200
• EC Number: 208-257-2
• MDL number: MFCD00006912
• Beilstein/REAXYS Number: 5282243
• Assay: ≥98% (HPLC)
• Form: powder

Properties

• Product Name: Citrinin, from Penicillium citrinum, ≥98% (HPLC)
• biological source: Penicillium citrinum
• Quality Segment: 200
• assay: ≥98% (HPLC)
• form: powder
• storage temp.: 2-8°C
• SMILES string: C[C@H]1OC=C2C(O)=C(C(O)=O)C(=O)C(C)=C2[C@@H]1C
• InChI: 1S/C13H14O5/c1-5-7(3)18-4-8-9(5)6(2)11(14)10(12(8)15)13(16)17/h4-5,7,15H,1-3H3,(H,16,17)/t5-,7-/m1/s1
• InChI key: CQIUKKVOEOPUDV-IYSWYEEDSA-N

Description

General description

Citrinin is a mycotoxin from Penicillium citrinin[1] that comprises a quinone methide component.[2]

Application

Citrinin has been used as:

• a standard for calibration curve preparation for citrinin quantification Monascus purpureus ATCC 36928
• an internal standard in thin layer chromatography (TLC) for characterizing the citrinin from Aspergillus and Penicillium strains[3]
• standard to characterize citrinin for rotten apples TLC[4]

Biochem/physiol Actions

Citrinin is a predominant contaminant in agriculture supplies and food. It exhibits genotoxic, embryotoxic, and teratogenic properties.[1] It is hepatonephrotoxin and a potent mycotoxin in rice grains.[2]

Safety Information

• pictograms: GHS06,GHS08
• signalword: Danger
• hcodes: H301 + H311 + H331,H351
• pcodes: P202 - P261 - P280 - P301 + P310 - P302 + P352 + P312 - P304 + P340 + P311
• Hazard Classifications: Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Carc. 2
• Storage Class: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• wgk: WGK 3
• ppe: Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges