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GC Analysis of Volatiles in Roasted Coffee Beans on Omegawax after SPME using a 50/30 μm DVB/Carboxen/PDMS Fiber

GC Analysis of Volatiles in Roasted Coffee Beans on Omegawax after SPME using a 50/30 μm DVB/Carboxen/PDMS Fiber application for SPME, suitable for GC

Materiais

Fibra para SPME

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Conjunto de fibras para SPME de divinilbenzeno-carboxeno-polidimetilsiloxano (DVB/CAR/PDMS)

needle size 24 ga, StableFlex, for use with autosampler

coluna analítica

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Omegawax Capillary GC Column

L × I.D. 30 m × 0.25 mm, df 0.25 μm

componente de fase móvel

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Acetato de etila

anhydrous, 99.8%

padrão

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p-Cymene

analytical standard

Methyl acetate

analytical standard

α-Terpinene

≥95.0% (GC)

γ-Terpinene

analytical standard

2,3-Butanedione

analytical standard

Piridina

anhydrous, 99.8%

2,5-Dimethylpyrrole

98%

3,4-Hexanedione

95%

2,3-Dihydro-5-methylfuran

97%

2,5-Dimethylfuran

99%

3-Ethylpyridine

≥98%, FG

2-Ethylpyrazine

≥98%, FG

3-Penten-2-one

≥70%

2-Methylpyrazine

≥99%

Acetoin

primarily dimer, ≥95%, FG

Álcool etílico, puro

200 proof, anhydrous, ≥99.5%

2-Acetyl-1-methylpyrrole

≥98%, FG

Pyrrole-2-carboxaldehyde

98%

2-Butanona

certified reference material, 2000 μg/mL in methanol: water (9:1)

Linalool

analytical standard

Linalyl acetate

analytical standard

2,3-Hexanedione

analytical standard

2,3-Pentanedione

analytical standard

Pyrazine

analytical standard

Furfural

analytical standard

Hexanal

analytical standard

5-Methylfurfural

analytical standard

Furfuryl acetate

analytical reference material

Pyrrole

analytical standard

Furfuryl alcohol

analytical standard

2-Methylfuran

analytical standard

2,5-Dimethylpyrazine

analytical standard

γ-Butirolactona

analytical standard

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Suporte de fibra para SPME

for use with manual sampling

Suporte de fibra para SPME

for use with CTC CombiPAL and Gerstel MPS2

CONDITIONS

sample/matrix

2 g of coffee beans

SPME fiber

50/30 μm divinylbenzene/Carboxen on polydimethylsiloxane on a StableFlex fiber (57329-U)

extraction

headspace, with a pre-equilibration period of 10 min. at 60 °C, and then a fiber exposure of 40 min. at 60 °C, agitated in an alternate clockwise-anticlockwise rotation mode at 500 rpm

desorption process

260 °C for 5 min

column

Omegawax 250, 30 m x 0.25 mm I.D., 0.25 μm (24136)

oven

40 °C (5 min), 4 °C/min to 230 °C, 50 °C/min to 280 °C (2 min)

inj. temp.

260 °C

detector

MS, m/z 40-400

carrier gas

helium, 34.8 cm/sec constant

injection

splitless

scan range

m/z 40-400

sample

Roasted coffee

liner

0.75 mm I.D. SPME/Splitless (2633901)

Descrição

Nota de análise

Headspace-SPME followed by GC analysis was used in this application to analyze volatile compounds in roasted coffee. SPME is ideal for analyzing the headspace of solid samples like coffee beans. The Carboxen/DVB/PDMS fiber is the fiber of choice for analyzing the wide range of analytes commonly found in roast coffee beans.The relatively polar Omegawax 250 GC column provided high resolution.

Informações legais

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