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1.04368

Hexane, mixture of isomers

≥95% (GC), suitable for UV/Vis spectroscopy, EMPLURA®

Synonym(s):

Hexane, n-Hexane

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About This Item

Linear Formula:
CH3(CH2)4CH3
CAS Number:
Molecular Weight:
86.18
UNSPSC Code:
12191502
EC Index Number:
203-777-6
NACRES:
NA.21
Beilstein/REAXYS Number:
1730733
MDL number:
Assay:
≥95% (GC)
Technique(s):
UV/Vis spectroscopy: suitable
Bp:
69 °C (lit.)
Vapor pressure:
256 mmHg ( 37.7 °C), 5.2 psi ( 37.7 °C), ~132 mmHg ( 20 °C)
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Product Name

n-Hexane, EMPLURA®

vapor density

~3 (vs air)

Quality Level

vapor pressure

256 mmHg ( 37.7 °C), 5.2 psi ( 37.7 °C), ~132 mmHg ( 20 °C)

product line

EMPLURA®

assay

≥95% (GC)

form

liquid

autoignition temp.

453 °F

potency

25000 mg/kg LD50, oral (Rat), >2000 mg/kg LD50, skin (Rabbit)

expl. lim.

7.7 %

technique(s)

UV/Vis spectroscopy: suitable

impurities

≤0.005% Free acid (as acetic acid), ≤0.02% Water

refractive index

n20/D 1.375 (lit.)

kinematic viscosity

0.50 cSt(20 °C)

bp

69 °C (lit.)

mp

−95 °C (lit.)

transition temp

flash point -22 °C

density

0.659 g/mL at 25 °C (lit.)

storage temp.

2-30°C

SMILES string

CCCCCC

InChI

1S/C6H14/c1-3-5-6-4-2/h3-6H2,1-2H3

InChI key

VLKZOEOYAKHREP-UHFFFAOYSA-N

General description

EMPLURA® is our low-cost alternative to high-purity qualities. With EMPLURA we offer a range of solvents for a plurality of basic applications in non-regulated industries and for less demanding applications, preparative laboratory work and cleaning purposes. EMPLURA solvents provide adequate specifications with the most important parameters.

Analysis Note

Purity (GC): ≥ 95.0 %
Identity (IR): conforms
Free acid (as acetic acid): ≤ 0.005 %
Density (d 20 °C/ 4 °C): 0.6590 - 0.6620
Readily carbonizable substances: conforms
Water: ≤ 0.02 %

Legal Information

EMPLURA is a registered trademark of Merck KGaA, Darmstadt, Germany

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This Item
1.070231.043671.04371
technique(s)

UV/Vis spectroscopy: suitable

technique(s)

-

technique(s)

-

technique(s)

gas chromatography (GC): suitable

assay

≥95% (GC)

assay

≥98.5% (Σ hexane isomers + methylcyclopentane )

assay

≥99% (GC)

assay

≥98% (GC)

Quality Level

200

Quality Level

200

Quality Level

300

Quality Level

100

form

liquid

form

liquid

form

liquid

form

liquid

expl. lim.

7.7 %

expl. lim.

7.7 %

expl. lim.

7.7 %

expl. lim.

7.7 %

refractive index

n20/D 1.375 (lit.)

refractive index

n20/D 1.375 (lit.)

refractive index

n20/D 1.375 (lit.)

refractive index

n20/D 1.375 (lit.)


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signalword

Danger

Hazard Classifications

Aquatic Chronic 2 - Asp. Tox. 1 - Flam. Liq. 2 - Repr. 2 - Skin Irrit. 2 - STOT RE 1 Inhalation - STOT SE 3

target_organs

Central nervous system, Nervous system

Storage Class

3 - Flammable liquids

wgk

WGK 3

flash_point_f

-7.6 °F - closed cup

flash_point_c

-22 °C - closed cup



Certificates of Analysis (COA)

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Global Trade Item Number

SKUGTIN
104368100004022536050614
104368901104027269350581
104368250104061838825971
104368619004022536050676
104368252104061838825988
104368902704061838825995
104368052104061838825964
104368919004022536050683
104368050104061838825957
104368251104027269060237
104368250004022536050638
104368602504022536050669
104368922104061838826008

Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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