Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
Kluczowe dokumenty
P51559
Propionyl chloride
98%
Synonim(y):
Chloro ethyl ketone, Ethyl chloroform, Propionic acid chloride, Prorionyl chloride
Wybierz wielkość
148,00 zł
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About This Item
148,00 zł
Polecane produkty
gęstość pary
3.2 (vs air)
Poziom jakości
Próba
98%
współczynnik refrakcji
n20/D 1.404 (lit.)
bp
77-79 °C (lit.)
mp
−94 °C
gęstość
1.059 g/mL at 25 °C (lit.)
ciąg SMILES
CCC(Cl)=O
InChI
1S/C3H5ClO/c1-2-3(4)5/h2H2,1H3
Klucz InChI
RZWZRACFZGVKFM-UHFFFAOYSA-N
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Opis ogólny
Zastosowanie
- To convert anisole to 4-methoxypropiophenone and 2-methoxynaphthalene to 1-propio-2-methoxynaphthalene in the presence of Indium(III) chloride (InCl3) impregnated mesoporous Si-MCM-41 catalyst.[1]
It can also be used:
- For chlorination in the presence of sulfuryl chloride and peroxides to form α-chloropropionyl chloride and β-chloropropionyl chloride.[2]
- In reaction with (hydroxypropyl)cellulose to form the propanoate ester, [(propionyloxy)propyl]cellulose.[3]
Hasło ostrzegawcze
Danger
Zwroty wskazujące rodzaj zagrożenia
Zwroty wskazujące środki ostrożności
Klasyfikacja zagrożeń
Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B
Zagrożenia dodatkowe
Kod klasy składowania
3 - Flammable liquids
Klasa zagrożenia wodnego (WGK)
WGK 1
Temperatura zapłonu (°F)
42.8 °F - closed cup
Temperatura zapłonu (°C)
6 °C - closed cup
Środki ochrony indywidualnej
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
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Certyfikaty analizy (CoA)
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Klienci oglądali również te produkty
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How is shipping temperature determined? And how is it related to the product storage temperature?
1 answer-
Helpful?
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How can I determine the shelf life / expiration / retest date of this product?
1 answer-
If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdfHelpful?
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How to do assy by titration with naoh solution
1 answer-
This product is tested by silver nitrate titration. The method is considered proprietary, the link below describes the general principle and offers a basic protocol:
https://www.canterbury.ac.nz/media/documents/science-outreach/chloride_volhard.pdf
Please refer to the literature for sodium hydroxide methods. The reference below may be helpful.
https://www.sciencedirect.com/science/article/abs/pii/B9780124115187000056Helpful?
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