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For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf
Kluczowe dokumenty
361941
Di-tert-butyl dicarbonate
≥99%, for peptide synthesis, ReagentPlus®
Synonim(y):
Boc anhydride, Di-tert-butyl pyrocarbonate
Wybierz wielkość
196,00 zł
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About This Item
196,00 zł
Polecane produkty
Nazwa produktu
Di-tert-butyl dicarbonate, ReagentPlus®, ≥99%
Poziom jakości
linia produktu
ReagentPlus®
Próba
≥99%
Formularz
solid or liquid
współczynnik refrakcji
n20/D 1.409 (lit.)
bp
56-57 °C/0.5 mmHg (lit.)
mp
23 °C (lit.)
gęstość
0.95 g/mL at 25 °C (lit.)
Zastosowanie
peptide synthesis
grupa funkcyjna
carbonate
temp. przechowywania
2-8°C
ciąg SMILES
CC(C)(C)OC(=O)OC(=O)OC(C)(C)C
InChI
1S/C10H18O5/c1-9(2,3)14-7(11)13-8(12)15-10(4,5)6/h1-6H3
Klucz InChI
DYHSDKLCOJIUFX-UHFFFAOYSA-N
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Zastosowanie
- As a reagent to introduce Boc protecting group for the amine functionalities.[1][2]
- To prepare tert-butyl ethers and Boc-alcohols in presence of Lewis acid catalyst.[3]
- As a carboxylating agent for the preparation of a variety of tert-butyl carboxylates.[4]
- For the conversion of amines to corresponding isocyanates, carbamates and urea derivatives.[4]
- As a coupling reagent for anchoring various carboxylic acids to hydroxymethylated resins.[5]
- To synthesize quinolinones and 2-(pseudo)haloquinolines from 2-alkenylanilines in presence of DMAP as a catalyst.[6]
Ostrzeżenie
Informacje prawne
Hasło ostrzegawcze
Danger
Zwroty wskazujące rodzaj zagrożenia
Zwroty wskazujące środki ostrożności
Klasyfikacja zagrożeń
Acute Tox. 1 Inhalation - Eye Dam. 1 - Flam. Liq. 3 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3
Organy docelowe
Respiratory system
Kod klasy składowania
3 - Flammable liquids
Klasa zagrożenia wodnego (WGK)
WGK 3
Temperatura zapłonu (°F)
98.6 °F - closed cup
Temperatura zapłonu (°C)
37 °C - closed cup
Środki ochrony indywidualnej
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
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How is shipping temperature determined? And how is it related to the product storage temperature?
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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